Gold-catalyzed intermolecular hydroamination of allenes: First example of the use of an aliphatic amine in hydroamination

摘要

Treatment of allenes with morpholine in the presence of cationic gold(I) catalyst ill toluene at 80 degrees C gave the corresponding allylic airlines in good to moderate yields. To the best of our knowledge. this is the first example for carrying out the gold-catalyzed intermolecular hydroamination with an aliphatic amine.