Concise synthesis of a steroid C/D-ring system using a bicyclo[3.2.1]octane chiral building block: A new route to 25-hydroxy-Grundmann's ketone

Hanada K.; Miyazawa N.; Nagata H.; Ogasawara K.

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Concise synthesis of a steroid C/D-ring system using a bicyclo[3.2.1]octane chiral building block: A new route to 25-hydroxy-Grundmann's ketone

机译：使用双环[3.2.1]辛烷手性构件的甾类C / D环系统的简捷合成：25-羟基-格伦德曼酮的新途径

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A concise route to a steroid C/D-ring system leading to 25-hydroxy-Grundmann's ketone has been developed along with a new chemical resolution of the chiral starting material containing a bicyclo[3.2.1]octane framework. [References: 17]

机译：已开发出一条通向类固醇C / D环系统的简明路线，该系统可生成25-羟基-格伦德曼酮，并提出了一种含有双环[3.2.1]辛烷骨架的手性原料的新化学拆分方法。 [参考：17]

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《Synlett》 |2002年第1期|共3页
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Hanada K.; Miyazawa N.; Nagata H.; Ogasawara K.;
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1. Concise synthesis of a steroid C/D-ring system using a bicyclo[3.2.1]octane chiral building block: A new route to 25-hydroxy-Grundmann's ketone [J] . Hanada K., Miyazawa N., Nagata H., Synlett . 2002,第1期

机译：使用双环[3.2.1]辛烷手性构件的甾类C / D环系统的简捷合成：25-羟基-格伦德曼酮的新途径
2. A concise enantiocontrolled route to yohimbones using a bicyclo[3.2.1]octane chiral building block [J] . Norio Miyazawa, Kunio Ogasawara Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2002,第27期

机译：使用双环[3.2.1]辛烷手性构件的简明对苯二酚的对映体控制路线
3. A New Route to (+)-Estrone Using a Bicyclo(3.2.1)octane Chiral Building Block. [J] . Hanada K, Miyazawa N, Ogasawara K Chemical and Pharmaceutical Bulletin . 2003,第1期

机译：使用双环（3.2.1）辛烷手性构件的（+）-雌激素的新路线。
4. Biotransformations in Natural Product Synthesis -Efficient Access to Chiral Building Blocks [C] . Diana Sandkuhl, Thomas Fischer, Jorg Pietruszka European Symposium on Organic Chemistry . 2009

机译：自然产品综合的生物转化 - 对手性建筑块的效率接近
5. I. BRIDGED TRANS-CYCLOHEPTENES: BICYCLO(3.2.2)NON-1-ENE, BICYCLO(3.2.2)NON-1(7)-ENE, BICYCLO(3.2.1)OCT-1-ENE, AND BICYCLO(3.2.1)OCT-1(7)-ENE. II. NEOPENYL REARRANGEMENTS: THE INTERCONVERSIONS OF BICYCLO(3.2.2)NON-1-YL, BICYCLO(3.2.1)-OCTANE-1-METHYL, AND BICYCLO(2.2.2)OCTANE-1-METHYL SYSTEMS. [D] . CHONG, JOSHUA ANTHONY. 1971

机译：I.桥接跨环蛋白：双环（3.2.2）NON-1-ENE，双环（3.2.2）NON-1（7）-ENE，双环（3.2.1）OCT-1-ENE和双环（3.2） .1）OCT-1（7）-ENE。二。新戊基重排：Bicyclo（3.2.2）NON-1-YL，BICYCLO（3.2.1）-OCTANE-1-甲基和BICYCLO（2.2.2）OCTANE-1-甲基系统的互换。
6. Synthesis of Highly Functionalised Enantiopure Bicyclo3.2.1- octane Systems from Carvone [O] . Antonio Abad, Consuelo Agulló, Ana C. Cuñat, 2004

机译：由香芹酮合成高功能对映纯双环3.2.1-辛烷体系
7. A New Route to (+)-Estrone Using a Bicyclo3.2.1octane Chiral Building Block. [O] . Keisuke Hanada, Norio Miyazawa, Kunio Ogasawara 2003

机译：使用双环3.2.1辛烷手性积木的新途径（+） - 雌激素。

Concise synthesis of a steroid C/D-ring system using a bicyclo[3.2.1]octane chiral building block: A new route to 25-hydroxy-Grundmann's ketone

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