PEG-supported imidazolium chloride: A highly efficient and reusable reaction medium for the Heck reaction

Wang LA; Zhang YH; Xie CS; Wang YG

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PEG-supported imidazolium chloride: A highly efficient and reusable reaction medium for the Heck reaction

机译：PEG负载的咪唑氯化物：一种用于Heck反应的高效且可重复使用的反应介质

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摘要

Pd(OAc)(2) in [PEGmim][Cl] constituted a highly efficient and recyclable catalytic system for the Heck reaction of aryl bromides and activated aryl chlorides in the absence of ligands.

机译：[PEGmim] [Cl]中的Pd（OAc）（2）构成了高效且可回收的催化体系，用于在不存在配体的情况下进行芳基溴化物和活化的芳基氯化物的Heck反应。

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来源
《Synlett》 |2005年第12期|共4页
作者
Wang LA; Zhang YH; Xie CS; Wang YG;
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原文格式 PDF
正文语种 eng
中图分类有机化学;
关键词
Heck reaction; ionic liquids; PEG; CROSS-COUPLING REACTIONS; IONIC LIQUID CATALYSIS; ARYL CHLORIDES; POLY(ETHYLENE GLYCOL); PALLADIUM NANOPARTICLES; RECYCLABLE CATALYST; CARBENE COMPLEXES; MODIFIED ZEOLITES; ACTIVE CATALYST; MOLTEN-SALT;

机译：Heck反应;离子液体;PEG;交叉偶联反应;离子液体催化;芳族氯化物;聚乙二醇;

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专利

1. PEG-supported imidazolium chloride: A highly efficient and reusable reaction medium for the Heck reaction [J] . Wang LA, Zhang YH, Xie CS, Synlett . 2005,第12期

机译：PEG负载的咪唑氯化物：一种用于Heck反应的高效且可重复使用的反应介质
2. An imidazolium-based phosphinite ionic liquid (IL-OPPh2) as a reusable reaction medium and Pd-II ligand in Heck reactions of aryl halides with styrene and n-butyl acrylate [J] . Iranpoor N, Firouzabadi H, Azadi R European journal of organic chemistry . 2007,第13期

机译：咪唑基次膦酸酯离子液体（IL-OPPh2）作为芳基卤化物与苯乙烯和丙烯酸正丁酯的Heck反应中可重复使用的反应介质和Pd-II配体
3. Imidazolium chloride-Co(III) complex immobilized on Fe3O4@SiO2 as a highly active bifunctional nanocatalyst for the copper-, phosphine-, and base-free Heck and Sonogashira reactions [J] . Kazemnejadi Milad, Alavi G. Seyyedeh Ameneh, Rezazadeh Zinat, Green chemistry . 2019,第7期

机译：Imidazolium-Co（III）复合物固定在Fe3O4 @ SiO 2上作为高活性双官能纳米催化剂，用于铜，膦 - ，免疫骨骼和Sonogashira反应
4. Mizoroki-Heck Arylation of alpha,beta-Unsaturated Acids with a Fluorous Ether,F-626:Fast Separation of Products and Efficient Recycling of a Reaction Medium Containing Catalyst [C] . Ilhyong, Takahide Fukuyama, Masashi Arai.Hiroshi, Symposium on Organometallic Chemistry . 2003

机译：用氟醚，F-626的α，β-不饱和酸的Mizoroki-Heck芳基化，F-626：快速分离产品和含催化剂的反应介质的有效回收
5. Michael–Heck Approach towards the Synthesis of Highly Functionalized Polyalkyl Furans and Application of the Vinylogous Michael–Heck Reaction towards the Total Synthesis of Furanosesquiterpenes and Furanoeremophilanes [D] . Chen, Yi-Jang Violet. 2021

机译：迈克尔 - Heck探讨了高官能化聚烷基呋喃的合成及乙烯基迈克尔 - Heck反应对呋喃孢素Quiterpenes和呋喃胺磷酸的总合成
6. Palladium(II)/Cationic 22’-Bipyridyl System as a Highly Efficient and Reusable Catalyst for the Mizoroki-Heck Reaction in Water [O] . Shao-Hsien Huang, Jun-Rong Chen, Fu-Yu Tsai 2010

机译：钯（II）/阳离子22-联吡啶系统是水中Mizoroki-Heck反应的高效且可重复使用的催化剂
7. Highly Efficient and Reusable Supported Pd Catalysts for Suzuki-Miyaura Reactions of Aryl Chlorides [O] . -1

机译：高效可重复使用的支持芳基氯化物反应的PD催化剂

PEG-supported imidazolium chloride: A highly efficient and reusable reaction medium for the Heck reaction

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