A stereoselective synthesis of (E)-alpha-stannylvinyl sulfones via palladium-catalyzed hydrostannylation of acetylenic sulfones

Cai MZ; Chen GQ; Hao WY; Wang D

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A stereoselective synthesis of (E)-alpha-stannylvinyl sulfones via palladium-catalyzed hydrostannylation of acetylenic sulfones

机译：钯催化炔属砜加氢苯乙烯基化立体选择性合成（E）-α-锡烷基乙烯基砜

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摘要

Palladium-catalyzed hydrostannylation of acetylenic sulfones with Bu3SnH in benzene at room temperature afforded stereoselectively (E)-alpha-stannylvinyl sulfones in good to high yields.

机译：在室温下，用Bu3SnH在苯中的钯催化炔属砜加氢苯乙烯基化反应可以很好地获得高选择性的立体选择性（E）-α-锡烷基乙烯基砜。

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《Synlett》 |2006年第20期|共3页
作者
Cai MZ; Chen GQ; Hao WY; Wang D;
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正文语种 eng
中图分类有机化学;
关键词
hydrostannylation; acetylenic sulfone; palladium; (E)-alpha-stannylvinyl sulfone; stereoselective synthesis; ADDITION-REACTIONS; COUPLING REACTIONS; VINYLSTANNANES; OLEFINS; STANNYLACETYLENES; HYDROZIRCONATION; ALLYLATION; 1; 4-DIENES; REACTIVITY; SULFOXIDES;

机译：加氢苯乙烯化;炔砜;钯;（E）-α-苯乙烯基乙烯基砜;立体选择性合成;加成反应;偶联反应;乙烯基锡;烯烃;苯乙烯基;加氢锆;烯丙基化;1;4-二烯;反应活性;硫化;

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1. A stereoselective synthesis of (E)-alpha-stannylvinyl sulfones via palladium-catalyzed hydrostannylation of acetylenic sulfones [J] . Cai MZ, Chen GQ, Hao WY, Synlett . 2006,第20期

机译：钯催化炔属砜加氢苯乙烯基化立体选择性合成（E）-α-锡烷基乙烯基砜
2. One-Pot Stereoselective Synthesis of (Z)-1,2-Disubstituted Vinyl Sulfones by Hydrostannylation-Stille Tandem Reaction of Acetylenic Sulfones [J] . Guiqin Chen, Yan Yu, Mingzhong Cai Synthetic Communications . 2009,第7a9期

机译：乙炔砜的氢化苯乙烯-斯蒂尔串联反应一锅立体选择性合成（Z）-1,2-二取代的乙烯基砜
3. A One-Pot, Stereoselective Synthesis of 1,3- and 1,4-Dienyl Sulfones by Hydrostannylation-Stille Tandem Reaction of Tributyltin Hydride with Acetylenic Sulfones and Alkenyl or Allylic Halides [J] . Mingzhong Cai, Guiqin Chen, Wenyan Hao Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2007,第8期

机译：三丁基锡氢化物与乙炔砜和烯基或烯丙基卤化物的氢化苯乙烯-斯蒂尔串联反应一锅，立体选择性合成1,3-和1,4-二烯基砜
4. Synthesis of poly(aryl sulfone benzimidazole) sulfone [C] . Guanjun Chang, Lin Zhang, Runxiong Lin International Conference on Advanced Engineering Materials and Technology . 2011

机译：聚（芳基砜苯并咪唑）砜的合成
5. Use of an acetylenic sulfone as an alkene dipole equivalent in the total synthesis of (+,-)-pumiliotoxin C. [D] . Nakajima, Katsumasa. 1997

机译：在（+，-）-pumiliotoxin C的全合成中使用乙炔砜作为烯烃偶极当量。
6. Palladium-Catalyzed Intramolecular Oxidative Arylationsfor the Synthesis of Fused Biaryl Sulfones [O] . Joydev K. Laha, *, Shubhra Sharma 2018

机译：钯催化的分子内氧化芳基化熔融联芳基砜的合成
7. A Highly Stereoselective Synthesis of (-)-(ent)-Julifloridine from the Cyclization of an Alanine-Derived Chloroamine with an Acetylenic Sulfone [O] . -1

机译：从亚氨基衍生的氯胺的环化与乙酰亚砜的环化高度立体化合成（ - ） - （ENT）-Julifloridine
8. Acetylene Terminated Sulfone Resin Precursors of Tailored Length via a Modified Ullmann Ether Synthesis [R] . Unroe, M. R., Hedberg, F. L. 1985

机译：通过改进的乌尔曼醚合成定制长度的乙炔封端砜树脂前体

A stereoselective synthesis of (E)-alpha-stannylvinyl sulfones via palladium-catalyzed hydrostannylation of acetylenic sulfones

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