Direct Synthesis of 1,2-Diketones by Catalytic Aerobic Oxidative Decarboxylation of 1,3-Diketones with Iodine and Base under Irradiation of Fluorescent Light

Norihiro Tada; Motoki Shomura; Hiroki Nakayama; Tsuyoshi Miura; Akichika Itoh

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Direct Synthesis of 1,2-Diketones by Catalytic Aerobic Oxidative Decarboxylation of 1,3-Diketones with Iodine and Base under Irradiation of Fluorescent Light

机译：碘和碱在荧光灯照射下1,3-二酮催化好氧氧化脱羧直接合成1,2-二酮

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摘要

We report a catalytic direct synthesis of 1,2-diketone from 1,3-diketone through iodine/base-catalyzed aerobic photo-oxidation under visible-light irradiation of fluorescent lamp.

机译：我们报告了在可见光的荧光灯照射下，通过碘/碱催化的有氧光氧化作用，由1,3-二酮催化直接合成1,2-二酮。

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来源
《Synlett》 |2010年第13期|共5页
作者
Norihiro Tada; Motoki Shomura; Hiroki Nakayama; Tsuyoshi Miura; Akichika Itoh;
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正文语种 eng
中图分类有机化学理论、物理有机化学;
关键词
photooxidation; iodine; aerobic; 1; 3-diketone; 1; 2-diketone;

机译：光氧化碘好氧1;3-二酮1;2-二酮;

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1. Direct Synthesis of 1,2-Diketones by Catalytic Aerobic Oxidative Decarboxylation of 1,3-Diketones with Iodine and Base under Irradiation of Fluorescent Light [J] . Norihiro Tada, Motoki Shomura, Hiroki Nakayama, Synlett . 2010,第13期

机译：碘和碱在荧光灯照射下1,3-二酮催化好氧氧化脱羧直接合成1,2-二酮
2. Catalytic Oxidative Cleavage of 1,3-Diketones to Carboxylic Acids by Aerobic Photooxidation with Iodine [J] . Norihiro Tada, Motoki Shomura, Lei Cui, Synlett . 2011,第19期

机译：碘的好氧光催化将1，3-二酮催化氧化分解为羧酸
3. Synthesis of 1,2-Diketones via a Metal-Free, Visible-Light-Induced Aerobic Photooxidation of Alkynes [J] . Liu Xu, Cong Tiantian, Liu Ping, The Journal of Organic Chemistry . 2016,第16期

机译：通过无金属，可见光诱导的炔烃有氧光氧化反应合成1,2-二酮
4. Synthesis, characterization and photoiuminescence of 1,1'-thiene-2,5-diyldibutane-1,3-diketone [C] . Guang-Ming Xia, Mu-Wei Ji, Ping Lu International Conference on Chemical Engineering and Advanced Materials . 2011

机译：1,1'-硫代烯-2,5-二粘蛋白-1,3-二酮的合成，表征和光敏性
5. Newly Developed Methods for Functionalization of Quaternary Carbons: Decarboxylative Allylation, Benzylation, and Arylation of Nitriles and the Asymmetric Baeyer-Villiger Oxidation of 1,3-Diketones [D] . Recio, Antonio, III 2012

机译：季碳官能化的新开发方法：腈的脱羧烯丙基化，苯甲酰化和丙烯酸化，以及1,3-二酮的不对称Baeyer-Villiger氧化
6. Iodine-Mediated Oxidative Rearrangement of αβ-UnsaturatedDiaryl Ketones: A Facile Access to 12-Diaryl Diketones [O] . Ajay H. Bansode, Gurunath Suryavanshi, * 2019

机译：碘介导的αβ-不饱和键的氧化重排二芳基酮：轻松获得12-二芳基二酮
7. Visible-Light-Induced Photocatalytic Oxidative Decarboxylation of Cinnamic Acids to 1,2-Diketones [O] . -1

机译：可见光诱导的光催化氧化纤维化甲基羧化肉桂酸至1,2-二酮

Direct Synthesis of 1,2-Diketones by Catalytic Aerobic Oxidative Decarboxylation of 1,3-Diketones with Iodine and Base under Irradiation of Fluorescent Light

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