CRYSTAL STRUCTURE OF THE (ET)(8)[HG4BR12-CENTER-DOT(PHCL)(2)] ORGANIC METAL AND THE (ET)(8)[HG4BR12-CENTER-DOT(MEPHCL)(2)] ORGANIC SEMICONDUCTOR - THE PRODUCTS OF THE SAME SYNTHESIS

摘要

X-ray study of the cation-radical salts (ET)(8)[Hg4Br12.(PhCl)(2)] (metal up to 90 K) and (ET)(8)[Hg4Br12.(MePhCl)(2)] (semiconductor) preparated in the same synthesis has shown considerable differences in the structures of their cationic and anionic layers. It is these differences that account for different electrophysical properties of these compounds. [References: 5]