Preparation and properties of conducting composites of polypyrrole and porous cross-linked polystyrene with and without supercritical carbon dioxide

摘要

Composites of polypyrrole (PPy) and porous cross-linked polystyrene (PCPS) were prepared using a two-step batch method proposed by Ruckenstein and Park. However, the solvent employed by Ruckenstein and Park (methanol) in the polymerization step of their method was replaced with supercritical CO_2. For comparison purposes, PPy/PCPS composites were also prepared using no solvent in the polymerization step. Conductivities as high as 10~-2 S cm~ -1 were obtained, with or without the use of supercritical CO_2. Uniformity of conductivity was determined via surface and bulk conductivity measurements, as well as by a new volume conductivity measurement that provides a measure of spatial (three-dimensional) distribution of the conducting component in the composite.The conductivity of composites prepared with or without the use of supercritical CO_2 conformed to the same percolation behavior with respect to the amount of PPy formed. The percolation threshold in all cases was as low as 4 wt. percent . The mechanical strength of the composites was found to be about the same as that of the host PCPS, as was the thermal stability. Therefore, the conductive component did not appear to adversely affect these properties of the host. Finally, the temperature behavior of the conductivity could be correlated with Mott's variable-range hopping (VRH) model for three-dimensional electronic transport.