Synthesis, crystal structure and electrical conductivity of (bmim) [Pd(dmit)_2]]_2 (bmim= 1-butyl-3-methylimidazolium, dmit=1,3 -dithiol-2-thiol-2-thione-4,5-dithiolate)

Chunyang Jia; Deqing Zhang; Wei Xu

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Synthesis, crystal structure and electrical conductivity of (bmim) [Pd(dmit)_2]]_2 (bmim= 1-butyl-3-methylimidazolium, dmit=1,3 -dithiol-2-thiol-2-thione-4,5-dithiolate)

机译：（bmim）[Pd（dmit）_2]] _ 2（bmim = 1-丁基-3-甲基咪唑鎓，dmit = 1,3-二硫醇-2-硫醇-2-硫酮-4,5的合成，晶体结构和电导率-二硫醇盐）

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The synthesis, structural characterization, and electrical conductivity studies of charge-transfer compound (bmim)[Pd(dmit)_2]_2 was described. This compound was obtained as small needles by electrocrystalization of (bmim)_2[Pd(dmit)_2]. Crystallographic parmeters for C_(20)H_(18)N_2S_(20)Pd_2: monoclinic system; space group: C2/c; a = 6.3718 (13), b = 14.543 (3), c = 36.339 (7) A alpha = 90, beta = 92.04 (3), gamma = 90; Z = 4, R = 0.0785 (I>2 sigma (I)).The room temperature conductivity of this salt is 1.2 S centre dot cm~(-1), and it shows metallic conducting state in the temperature range of 287- 245 K.

机译：描述了电荷转移化合物（bmim）[Pd（dmit）_2] _2的合成，结构表征和电导率研究。通过（bmim）_2 [Pd（dmit）_2]的电结晶获得小针状化合物。 C_（20）H_（18）N_2S_（20）Pd_2的晶体学参数：单斜晶系;空间群：C2 / c; a = 6.3718（13），b = 14.543（3），c = 36.339（7）A alpha = 90，beta = 92.04（3），gamma = 90; Z = 4，R = 0.0785（I> 2 sigma（I））。该盐的室温电导率为1.2 S中心点cm〜（-1），在287-245的温度范围内表现出金属导电状态K.

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《Synthetic Metals》 |2003年第3期|共2页
作者
Chunyang Jia; Deqing Zhang; Wei Xu;
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正文语种 eng
中图分类工程材料学;黑色金属材料;
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Organic conductor; Electrocrystalization;

机译：有机导体;电结晶;

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1. Synthesis, crystal structure and electrical conductivity of (bmim) [Pd(dmit)_2]]_2 (bmim= 1-butyl-3-methylimidazolium, dmit=1,3 -dithiol-2-thiol-2-thione-4,5-dithiolate) [J] . Chunyang Jia, Deqing Zhang, Wei Xu Synthetic Metals . 2003,第1a3期

机译：（bmim）[Pd（dmit）_2]] _ 2（bmim = 1-丁基-3-甲基咪唑鎓，dmit = 1,3-二硫醇-2-硫醇-2-硫酮-4,5的合成，晶体结构和电导率-二硫醇盐）
2. SYNTHESIS AND CRYSTAL STRUCTURE OF [GUANIDINIUM][NI(DMIT)(2)](2) AND [1,1-DIMETHYLGUANIDINIUM][NI(DMIT)(2)](2) (DMIT=2-THIOXA-1,3-DITHIOLE-4,5-DITHIOLATE) - INTERMOLECULAR ORBITAL INTEGRAL OVERLAP CALCULATIONS AND ELECTRICAL CONDUCTIVITIES [J] . Veldhuizen YSJ., Spek AL., Faulmann C., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1995,第1期

机译：[胍] [NI（DMIT）（2）]（2）和[1,1-二甲基胍] [NI（DMIT）（2）]（2）的合成和晶体结构（DMIT = 2-THIOXA-1,3 -DITHIOLE-4,5-DITHIOLATE）-分子间轨道积分重叠计算和电导率
3. A new molecular metal based on Pd(dmit)2: synthesis, structure and electrical properties of (C7H13NH)[Pd(dmit)(2)](2) (dmit(2-)=2-thioxo-1,3-dithiole-4,5-dithiolate) [J] . Naito T., Kobayashi H., Kobayashi A., Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology . 2001,第9期

机译：基于Pd（dmit）2的新型分子金属：（C7H13NH）[Pd（dmit）（2）]（2）（dmit（2-）= 2-thioxo-1,3-dithiole的合成，结构和电性能-4,5-二硫代）
4. Synthesis and Crystal Structure of the Flexible Ligand Coordination Polymer Co_3(bpd)_(5.5)(NCS)_6(NH_3)_n·2H_2O (bpd= 1,4-bis(4-pyridyl)-2,3-diaza-1,3-butadiene) [C] . Yuqi Liu, Yong Yang, Rui Yang, International Conference on Chemical Engineering, Metallurgical Engineering and Metallic Materials . 2013

机译：柔性配体配位聚合物的合成和晶体结构CO_3（BPD）_（5.5）（NCS）_6（NH_3） _ N·2H_2O（BPD = 1,4-双（4-吡啶基）-2,3-第二次 - 1,3-丁二烯）
5. Synthesis, characterization and crystal structures of homonuclear copper complexes with 1,3-bis(dimethylamino)-2-propanol as ligand. [D] . Zheng, Jian-Chuan. 1993

机译：以1,3-双（二甲基氨基）-2-丙醇为配体的同核铜配合物的合成，表征和晶体结构。
6. Synthesis Superoxide Dismutase Mimetic and Anticancer Activities of Metal Complexes of 22-Dimethylpentanedioic Acid(2dmepdaH2) and 33-Dimethylpentanedioic acid(3dmepdaH2): X-Ray Crystal Structures of Cu(3dmepda)(bipy)2· 6H2O and Cu(2dmepda)(bipy)(EtOH)2· 4EtOH(bipy = 22′Bipyridine) [O] . Michael Devereux, Malachy McCann, Denis OShea, 2006

机译：22-二甲基戊二酸（2dmepdaH2）和33-二甲基戊二酸（3dmepdaH2）的金属配合物的合成超氧化物歧化酶模拟和抗癌活性：Cu（3dmepda）（bipy） 2·6H2O的X射线晶体结构和Cu（2dmepda）（bipy）（EtOH） 2·4EtOH（Bipy = 22联吡啶）
7. Cation Dependence of Crystal Structure and Band Parameters in a Series of Molecular Conductors, β'-(Cation)[Pd(dmit)2]2 (dmit = 1,3-dithiole-2-thione-4,5-dithiolate) [O] . Reizo Kato, Cui Hengbo 2012

机译：一系列分子导体β'-（阳离子）[Pd（dmit）2] 2（dmit = 1,3-二硫代-2-硫酮-4,5-二硫代）的晶体结构和能带参数的阳离子依赖性
8. Synthesis, X-Ray Crystal Structure and Reactions of (closo-1,3-mu-2,3-mu(1,2-mu (eta2-3,4-CH2CH2C(CH3) =CHCH2CH2CH2)) -3-H-3-PPh3-3,1,2-RhC2 B9H9), a Metallocarbaborane Catalyst [R] . Delaney, M. S., Teller, R. G., Hawthorne, M. F. 1981

机译：（closo-1,3-mu-2,3-mu（1,2-mu（eta2-3,4-CH2CH2C（CH3）= CHCH2CH2CH2））-3-H-的合成，X-射线晶体结构和反应3-pph3-3,1,2-RhC2 B9H9），金属碳硼烷催化剂

Synthesis, crystal structure and electrical conductivity of (bmim) [Pd(dmit)_2]]_2 (bmim= 1-butyl-3-methylimidazolium, dmit=1,3 -dithiol-2-thiol-2-thione-4,5-dithiolate)

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