SYNTHESIS OF CYCLOPROPENONE-CONTAINING AMINO ACID MIMIC - ADDITION OF CYCLOPROPENYL CERIUM REAGENT TO ALPHA-AMINO ALDEHYDES

Tokuyama H.; Nakamura E.; Isaka M.

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SYNTHESIS OF CYCLOPROPENONE-CONTAINING AMINO ACID MIMIC - ADDITION OF CYCLOPROPENYL CERIUM REAGENT TO ALPHA-AMINO ALDEHYDES

机译：含环戊酮的氨基酸模拟物的合成-环戊基铈试剂与α-氨基酰胺的加成

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摘要

A novel amino acid mimic, 2-(2-amino-1-hydroxyalkyl)-cyclopropenone, has been prepared via chelation controlled addition of a cyclopropenyl cerium reagent to an alpha-amino aldehyde. [References: 16]

机译：通过将环丙烯基铈试剂螯合控制地添加到α-氨基醛中，已经制备了一种新型的氨基酸模拟物2-（2-氨基-1-羟烷基）-环丙烯酮。 [参考：16]

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《Synthetic Communications》 |1995年第13期|共8页
作者
Tokuyama H.; Nakamura E.; Isaka M.;
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正文语种 eng
中图分类有机化学;
关键词
Antibiotic penitricin; Organic-synthesis; General-synthesis; Isosteres; Ketals;

机译：抗生素青霉素;有机合成;一般合成;等排体;酮;

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1. SYNTHESIS OF CYCLOPROPENONE-CONTAINING AMINO ACID MIMIC - ADDITION OF CYCLOPROPENYL CERIUM REAGENT TO ALPHA-AMINO ALDEHYDES [J] . Tokuyama H., Nakamura E., Isaka M. Synthetic Communications . 1995,第13期

机译：含环戊酮的氨基酸模拟物的合成-环戊基铈试剂与α-氨基酰胺的加成
2. Synthesis of (S)- and (R)-1-(2-furyl)alkylamines and (S)- and (R)-alpha-amino acids through the addition of organometallic reagents to imines derived from (S)-valinol [J] . Alvaro G., Savoia D., Zoffoli A., Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 1998,第12期

机译：通过将有机金属试剂添加到衍生自（S）-缬氨醇的亚胺中来合成（S）-和（R）-1-（2-呋喃基）烷基胺以及（S）-和（R）-α-氨基酸
3. New C-Glycosylated ?±-Amino Acid Synthesis by Addition Reaction of an Amino Acid Organozinc Reagent on Carbohydrate-Derived Aldehydes [J] . Nicolas Boutard, Fr??d??ric Lab??gu?¨re, Yves Vidal, Synthetic Communications: An International Journal for Rapid Communication of Synthetic Organic Chemistry . 2012,第10期

机译：氨基酸有机锌试剂与碳水化合物衍生的醛加成反应合成新的C-糖基化α±氨基酸
4. Design and synthesis of chiral cyclic a,a-disubstituted alpha-amino acids and its peptides [C] . Yosuke Demizu, Masakazu Tanaka, Kosuke Anan International Peptide Symposium;European Peptide Symposium . 2005

机译：手性环状A，a - 二取代的α-氨基酸及其肽的设计与合成
5. ASYMMETRIC SYNTHESES OF ALPHA-AMINO ACIDS AND ALPHA-AMINO ALDEHYDES VIA ELECTROPHILIC SUBSTITUTION OF CHIRAL LITHIOCARBANIONS. [D] . DAVENPORT, KENNETH GERALD. 1982

机译：通过手性锂碳的亲电取代反应合成α-氨基酸和α-氨基醛。
6. Enantioselective Addition of Allyltin Reagents to Amino Aldehydes Catalyzed with Bis(oxazolinyl)phenylrhodium(III) Aqua Complexes [O] . Yukihiro Motoyama, Takatoshi Sakakura, Toshihide Takemoto, 2011

机译：双（恶唑啉基）苯基铑（III）水络合物催化烯丙基化试剂对氨基醛的对映选择性加成
7. Stereoselective Synthesis of Steroids and Related Compounds, IV. Addition of Cerium Reagents Derived from (Trimethylsilyl)propargyl Bromide to Aldehydes [O] . Peter Eckenberg, Ulrich Groth, Thomas Köhler 1994

机译：类固醇和相关化合物，IV的立体选择性合成。添加衍生自（三甲基甲硅烷基）丙氨酸溴乙烯至醛的铈试剂
8. Acyclic 'N'-Acyliminium Ions in the Synthesis of alpha-Amino Acids [R] . Mooiweer, H. H. 1990

机译：非环状'N'-酰基亚胺离子在α-氨基酸合成中的应用

SYNTHESIS OF CYCLOPROPENONE-CONTAINING AMINO ACID MIMIC - ADDITION OF CYCLOPROPENYL CERIUM REAGENT TO ALPHA-AMINO ALDEHYDES

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