FLUORINATION AT C2', C3' AND C5' OF NUCLEOSIDES WITH 1-CHLOROMETHYL-4-FLUORO-1,4-DIAZABICYCLO[2.2.2]OCTANE BIS(TETRAFLUOROBORATE) SELECTFLUOR(TM) REAGENT

Lal GS.

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FLUORINATION AT C2', C3' AND C5' OF NUCLEOSIDES WITH 1-CHLOROMETHYL-4-FLUORO-1,4-DIAZABICYCLO[2.2.2]OCTANE BIS(TETRAFLUOROBORATE) SELECTFLUOR(TM) REAGENT

机译：用1-氯甲基-4-氟-1,4-二氮杂双[2.2.2]辛基双（四氟硼酸）SELECTFLUOR（TM）试剂在核苷的C2'，C3'和C5'上进行氟化

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Electrophilic fluorination of thioaryl ethers on the sugar component of nucleosides with commercially available SELECTFLUOR(TM) reagent provides a new method for the synthesis of C2', C3' and C5' fluoronucleosides. [References: 16]

机译：用可商购的SELECTFLUOR TM试剂对核苷的糖成分上的硫代芳基醚进行亲电氟化，提供了一种合成C2'，C3'和C5'氟代核苷的新方法。 [参考：16]

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《Synthetic Communications》 |1995年第5期|共13页
作者
Lal GS.;
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正文语种 eng
中图分类有机化学;
关键词
Acid related-compounds; Xenon difluoride; Trifluoride; Analogs;

机译：酸相关化合物;二氟化氙;三氟化氙;类似物;

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1. FLUORINATION AT C2', C3' AND C5' OF NUCLEOSIDES WITH 1-CHLOROMETHYL-4-FLUORO-1,4-DIAZABICYCLO[2.2.2]OCTANE BIS(TETRAFLUOROBORATE) SELECTFLUOR(TM) REAGENT [J] . Lal GS. Synthetic Communications . 1995,第5期

机译：用1-氯甲基-4-氟-1,4-二氮杂双[2.2.2]辛基双（四氟硼酸）SELECTFLUOR（TM）试剂在核苷的C2'，C3'和C5'上进行氟化
2. N-Halogeno compounds. Part 20. Vicarious electrophilic fluorodemethy-lation of 1,3,5-trimethoxybenzene and 2,4,6-trimethoxytoluene with 1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)(Selectfluor~(TM)reagent F-TEDA-BR [J] . Banks R.Eric, Besheesh Mohamed K. Journal of Fluorine Chemistry . 1999,第0期

机译：N-Halogeno化合物。第20部分。1,3-，5-三甲氧基苯和2,4,6-三甲氧基甲苯与1-氯甲基-4-氟-1,4-二氮杂双环[2.2.2]辛烷双（四氟硼酸酯）（Selectfluor）的取代亲电氟甲基化〜（TM）试剂F-TEDA-BR
3. N-Halogeno compounds. Part 20. Vicarious electrophilic fluorodemethy-lation of 1,3,5-trimethoxybenzene and 2,4,6-trimethoxytoluene with 1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)(Selectfluor~(TM)reagent F-TEDA-BR [J] . Banks R.Eric, Besheesh Mohamed K. Journal of Fluorine Chemistry . 1999,第0期

机译：N-Halogeno化合物。第20部分。1,3-，5-三甲氧基苯和2,4,6-三甲氧基甲苯与1-氯甲基-4-氟-1,4-二氮杂双环[2.2.2]辛烷双（四氟硼酸酯）（Selectfluor）的取代亲电氟甲基化〜（TM）试剂F-TEDA-BR
4. Crystal structures of 1,4-diazabicyclo[2.2.2]octan-1-ium 4-nitrobenzoate dihydrate and 1,4-diazabicyclo[2.2.2]octane-1,4-diium bis(4-nitrobenzoate): the influence of solvent upon the stoichiometry of the formed salt [O] . Aina Mardia Akhmad Aznan, Zanariah Abdullah, Edward R. T. Tiekink 2014

机译：1,4-二氮杂双环[2.2.2]辛-1-鎓4-硝基苯甲酸二水合物和1,4-二氮杂双环[2.2.2]辛烷-1,4-二（4-硝基苯甲酸）的晶体结构：影响溶剂在形成的盐的化学计量比

FLUORINATION AT C2', C3' AND C5' OF NUCLEOSIDES WITH 1-CHLOROMETHYL-4-FLUORO-1,4-DIAZABICYCLO[2.2.2]OCTANE BIS(TETRAFLUOROBORATE) SELECTFLUOR(TM) REAGENT

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