A NEW METHOD FOR THE REDUCTIVE CLEAVAGE OF SE-SE BOND BY TITANOCENE DICHLORIDE ISOBUTYL-MAGNESIUM BROMIDE SYSTEM AND ITS APPLICATION IN SYNTHESIS OF SELENOESTER

Xu XH.; Huang X.

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A NEW METHOD FOR THE REDUCTIVE CLEAVAGE OF SE-SE BOND BY TITANOCENE DICHLORIDE ISOBUTYL-MAGNESIUM BROMIDE SYSTEM AND ITS APPLICATION IN SYNTHESIS OF SELENOESTER

机译：钛茂二茂铁异丁基溴化镁体系还原裂解SE-SE键的新方法及其在硒酯合成中的应用

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The reduction of diaryldiselenides by Cp2TiCl2/2i-BuMgBr/THF led to arylselenium complex of titanocene (Cp2TiSeAr). This species reacts smoothly with acidic anhydrides to give selenoesters. [References: 9]

机译：Cp2TiCl2 / 2i-BuMgBr / THF还原二芳基二硒化物导致钛茂的芳基硒配合物（Cp2TiSeAr）。该物质与酸性酸酐平稳反应，生成硒酸酯。 [参考：9]

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《Synthetic Communications》 |1997年第21期|共5页
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Xu XH.; Huang X.;
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正文语种 eng
中图分类有机化学;
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1. A NEW METHOD FOR THE REDUCTIVE CLEAVAGE OF SE-SE BOND BY TITANOCENE DICHLORIDE ISOBUTYL-MAGNESIUM BROMIDE SYSTEM AND ITS APPLICATION IN SYNTHESIS OF SELENOESTER [J] . Xu XH., Huang X. Synthetic Communications . 1997,第21期

机译：钛茂二茂铁异丁基溴化镁体系还原裂解SE-SE键的新方法及其在硒酯合成中的应用
2. CeCl_3/Sm System Induced Reductive Cleavage of the Se-Se Bond in Diaryl Diselenides: A Novel Method for the Synthesis of beta-Selenoesters and beta-Selenonitriles [J] . Xue Li, Songlin Zhang, Yulu Wang, Journal of the Chinese Chemical Society. . 2002,第6期

机译：CeCl_3 / Sm系统诱导二芳基二硒化物中Se-Se键的还原裂解：合成β-硒酸酯和β-硒腈的新方法
3. Zn/ZrCl_4 system induced reductive cleavage of the Se-Se bond in diaryl diselendies: a novel method for the synthesis of #beta#-selenoesters and #beta#-selenonitriles [J] . Songlin Zhang, Fengshou Tian Journal of Chemical Research. Synopses . 2001,第5期

机译：Zn / ZrCl_4系统诱导二芳基硒原子中硒-硒键的还原裂解：合成＃beta＃-硒酸酯和＃beta＃-硒腈的新方法
4. Synthesis,Characterization,and the Ethylene (co-)polymerization Behaviour of Half-titanocene Dichloride 2-aryliminoquinolin-8-olates [C] . Wei Huang, Wenjuan Zhang, Wen-Hua Sun 7th international symposium on high-tech polymer materials: Synthesis, characterization and applications . 2012

机译：半茂钛二氯化物2-芳基喹啉-8-酸酯的合成，表征及乙烯（共）聚合行为
5. I. SYNTHESIS AND PHYSICAL CHARACTERIZATION OF SELECTED POLYSTYRENE SUPPORTED PHTHALOCYANINE COMPLEXES. II. ELECTRON TRANSFER STUDY BETWEEN TITANOCENE DICHLORIDE AND REDUCED TITANOCENE DICHLORIDE ANION. [D] . GEBLER, MICHAEL DANIEL. 1982

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6. Synthesis and Biological Evaluation of Achiral Indole-Substituted Titanocene Dichloride Derivatives [O] . Anthony Deally, Frauke Hackenberg, Grainne Lally, 2012

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7. Synthesis of 1-Methyl-3-aryl-substituted titanocene and zirconocene dichlorides and crystal structure of Bisη5-1-methyl-3-(α, α-dimethylbenzyl) cyclopentadienyl titanium dichloride [O] . Qian YL, Qin XR, Huang JL, 2001

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8. Redox Catalysis Involving Substrate Photooxidation with Catalyst Regeneration bySubstrate Reduction. Simultaneous Oxidative C-H Bond Cleavage and Reductive C-S Bond Cleavage in Thioethers Catalyzed by W10O324- [R] . Chambers, R. C., Hill, C. L. 1990

机译：氧化还原催化与底物光氧化反应的催化剂再生通过底物还原。 W10O324催化的硫醚同时氧化C-H键断裂和还原C-s键断裂

A NEW METHOD FOR THE REDUCTIVE CLEAVAGE OF SE-SE BOND BY TITANOCENE DICHLORIDE ISOBUTYL-MAGNESIUM BROMIDE SYSTEM AND ITS APPLICATION IN SYNTHESIS OF SELENOESTER

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