Solvent-free aerobic chemoselective oxidation of beta-ionone catalyzed by N-hydroxyphthalimide/Co(acac)(2)

Gong NH; Tang RR; Zhou YP; Xu HF

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Solvent-free aerobic chemoselective oxidation of beta-ionone catalyzed by N-hydroxyphthalimide/Co(acac)(2)

机译：N-羟基邻苯二甲酰亚胺/ Co（acac）（2）催化的β-紫罗兰酮无溶剂有氧化学选择性氧化

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摘要

beta-Ionone was oxidized with O-2 under solvent-free conditions catalyzed by an N-hydroxyphthalimide/Co(acac)(2) system in mild conditions with high conversion and excellent selectivity to oxo-beta-ionone or 5,6-epoxy-beta-ionone in different reaction conditions, respectively.

机译：N-羟基邻苯二甲酰亚胺/ Co（acac）（2）系统在无溶剂的条件下，在温和的条件下以高转化率和对OXO-β-紫罗兰酮或5,6-环氧的优异选择性，将O-2氧化成β-紫罗兰酮-β-紫罗兰酮分别在不同的反应条件下。

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《Synthetic Communications》 |2008年第7期|共8页
作者
Gong NH; Tang RR; Zhou YP; Xu HF;
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正文语种 eng
中图分类有机化学;
关键词
aerobic oxidation; 5; 6-epoxy-beta-ionone; N-hydroxyphthalimide; oxo-beta-ionone; solvent free; N-HYDROXYPHTHALIMIDE; MOLECULAR-OXYGEN; DIOXYGEN; ALKENES; HYDROCARBONS; EPOXIDATION; ALCOHOLS; SALTS;

机译：好氧氧化;5;6-环氧-β-紫罗兰酮;N-羟基邻苯二甲酰亚胺;氧-β-紫罗兰酮;无溶剂;N-羟基邻苯二甲酰亚胺;分子氧;DIOXYGEN;烯烃;烃;环氧化合物;环氧;醇;盐;

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专利

1. Solvent-free aerobic chemoselective oxidation of beta-ionone catalyzed by N-hydroxyphthalimide/Co(acac)(2) [J] . Gong NH, Tang RR, Zhou YP, Synthetic Communications . 2008,第7期

机译：N-羟基邻苯二甲酰亚胺/ Co（acac）（2）催化的β-紫罗兰酮无溶剂有氧化学选择性氧化
2. Solvent-free aerobic chemoselective oxidation of beta-ionone catalyzed by N-hydroxyphthalimide/Co(acac)(2) [J] . Gong NH, Tang RR, Zhou YP, Synthetic Communications . 2008,第7a9期

机译：N-羟基邻苯二甲酰亚胺/ Co（acac）（2）催化的β-紫罗兰酮无溶剂有氧化学选择性氧化
3. Solvent-Free Aerobic Chemoselective Oxidation of β-Ionone catalyzed by N-Hydroxyphthalimide/Co(acac)₂ [J] . Synthetic Communications . 2008,第7期

机译：N-羟基邻苯二甲酰亚胺/ Co（acac）_{2 催化的无溶剂有氧化学选择性氧化β-紫罗兰酮}
4. Effective Aerobic Oxidation of p-Nitrotoiuene to p-nitrobenzoic acid Catalyzed by Manganese Dioxide and N-Hydroxyphthalimide [C] . Wei Wang, Bo Yan, Jun Jiang International Conference on Chemical Engineering and Advanced Materials . 2011

机译：用二氧化锰催化对硝基噻吩的P-硝基苯甲酸的有效性氧化和正羟苯二甲酰亚胺
5. Mechanistic studies of palladium-catalyzed 'Wacker type' intramolecular aerobic oxidative amination of alkenes and Development of safe and scalable continuous-flow methods for palladium-catalyzed aerobic oxidation [D] . Ye, Xuan 2010

机译：钯催化烯烃的“ Wacker型”分子内需氧氧化胺化的机理研究和开发安全，可扩展的连续流法进行钯催化的需氧氧化
6. Rapid Pd-Catalyzed Synthesis of Piperazine Scaffolds Under Aerobic and Solvent-Free Conditions [O] . Sean W. Reilly, Robert H. Mach -1

机译：有氧和无溶剂条件下钯催化快速合成哌嗪支架
7. Solvent-free aerobic oxidative cleavage of alkenes catalyzed by N-hydroxyphthalimide [O] . Dariusz Pyszny, Beata Orlińska 2017

机译：N-羟苯二甲酰亚胺催化的烯烃无溶剂的有氧氧化裂解

Solvent-free aerobic chemoselective oxidation of beta-ionone catalyzed by N-hydroxyphthalimide/Co(acac)(2)

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