Resonance light scattering method for the determination of anionic surfactant with acridine orange

摘要

The resonance Rayleigh scattering (RRS), second-order scattering (SOS) and frequency-double scattering (FDS) spectra of sodium dodecylbenzene sulfonate (SDBS) (anionic surfactant (AS)) with acridine orange (AO) system were studied. Experimental results showed that when lambda(cm) = lambda(ex) = 537 nm, the RRS peak of AO was greatly enhanced with the increase of SDBS concentration at a pH range of 1.8-4.0. The linear range of the calibration curve for SDBS was 0.028-8.71 mg L-1 with a detection limit of 8.36 mu g L-1 when the AO concentration was 2.5 x 10(-5) mol L-1. The method has been applied to the determination of trace amount of AS in environmental water samples with satisfactory results. In addition, when lambda(cm) = 321 nm and lambda(ex) = 642 nm, the intensity of FDS was proportional to the SDBS concentration ranging from 0.014 to 8.71 mg L-1 and the correlation coefficient was 0.993 with a detection limit of 4.31 mu g L-1; when lambda(cm) = 642 nm and lambda(ex) = 321 nm, the intensity of SOS was proportional to the SDBS concentration ranging from 0.050 to 8.71 mg L-1, and the correlation coefficient was 0.993 with a detection limit of 14.9 mu g L-1. (c) 2008 Elsevier B.V. All rights reserved.