Barium-modified NiO–YSZ/NiO–GDC cermet as new anode material for solid oxide fuel cells (SOFC)

摘要

The effect of Ba-impregnation within a bi-layered NiO–YSZ/NiO–GDC anode for solid oxide fuel cells (SOFC) has been investigated. The in situ formation of BZY/BCG proton conducting phases is proved by X-ray diffraction (XRD) and analyzed in detail by the Rietveldmethod. The integration of bariumwithin the cermetmicrostructure is also evidenced by Electron Microscopy, where the presence of BZY/BCG phases creates possible additional paths for proton conduction. Electrochemical impedance spectroscopy (EIS) analysis indicates that the proton conducting phases generate a global decrease in the total polarization resistance, and in particular in its charge transfer component.