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首页> 外文期刊>Solid state ionics >Synthesis and conductivities of the gamet-related Li ion conductors, Li(5)Ln(3)Sb(2)O(12) (Ln=La, Pr, Nd, Sm, Eu)
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Synthesis and conductivities of the gamet-related Li ion conductors, Li(5)Ln(3)Sb(2)O(12) (Ln=La, Pr, Nd, Sm, Eu)

机译:与配子有关的Li离子导体Li(5)Ln(3)Sb(2)O(12)的合成和电导率(Ln = La,Pr,Nd,Sm,Eu)

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摘要

In this paper the synthesis and conductivities of the garnet-related Li ion conductors, Li(5)Ln(3)Sb(2)O(12) (Ln = La, Pr, Nd, Sm, Eu), are reported. These phases show high Li ion conductivity, similar to previously reported for the related Li5La3M2O12 (M=Nb, Ta) materials. Neutron diffraction structural studies are also reported for Li5La3Sb2O12 indicating a cubic unit cell, space group Ia-3d, with Li located in two partially occupied sites.
机译:本文报道了与石榴石有关的Li离子导体Li(5)Ln(3)Sb(2)O(12)(Ln = La,Pr,Nd,Sm,Eu)的合成和电导率。这些相显示出高的锂离子电导率,类似于先前报道的有关Li5La3M2O12(M = Nb,Ta)材料。还报道了Li5La3Sb2O12的中子衍射结构研究,表明立方晶胞,空间群Ia-3d,其中Li位于两个部分占据的位置。

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