Complexes of 2-Mercaptopyrimidines with Metals in Sodium Azide Solution.Investigation of Composition and Reactivity by Iodine-Azide Reaction

Krystyna Janowicz; Jan Kurzawa

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Complexes of 2-Mercaptopyrimidines with Metals in Sodium Azide Solution.Investigation of Composition and Reactivity by Iodine-Azide Reaction

机译：叠氮化钠溶液中2-巯基嘧啶与金属的配合物叠氮化碘反应的组成和反应性研究

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The iodine-azide reaction selectively induced by sulfur(II) compounds has been used for the investigation of metal complexes with 2-mercaptopyrimidine and its ten homologues.Substitution of mercaptopirymidines ligands with azide ions at a milimolar level has been investigated.The studied complexes were arranged in the inertness series.The time of complex formation and their composition have been established.

机译：硫（II）化合物选择性诱导的碘-叠氮化物反应已用于研究2-巯基嘧啶及其十个同系物的金属配合物，研究了巯基吡啶亚胺配体被叠氮化物离子取代的分子团水平。建立了络合物形成的时间及其组成。

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《Chemia Analityczna》 |2008年第1期|共11页
作者
Krystyna Janowicz; Jan Kurzawa;
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正文语种 eng
中图分类分析化学;
关键词
Mercaptopyrimidines; Complexes; Iodine-azide reaction;

机译：巯基嘧啶;络合物;碘叠氮化物反应;

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1. Complexes of 2-Mercaptopyrimidines with Metals in Sodium Azide Solution.Investigation of Composition and Reactivity by Iodine-Azide Reaction [J] . Krystyna Janowicz, Jan Kurzawa Chemia Analityczna . 2008,第1期

机译：叠氮化钠溶液中2-巯基嘧啶与金属的配合物叠氮化碘反应的组成和反应性研究
2. Reactions of Metal Carbonyls with the Azide Ion and - vice versa - Reactions of Azido Complexes with Carbon Monoxide: Isocyanato Complexes. Analogous Reactions in NO+/N-3(-) Transition Metal Chemistry [1] [J] . Beck W, Fehlhammer WP Zeitschrift fur Anorganische und Allgemeine Chemie . 2010,第1期

机译：金属羰基与叠氮化物离子的反应，反之亦然-叠氮基络合物与一氧化碳的反应：异氰酸根合络合物。 NO + / N-3（-）过渡金属化学中的类似反应[1]
3. Cycloaddition reactivity studies of first-row transition metal-azide complexes, alkynes: An inorganic click reaction for metalloenzyme inhibitor synthesis [J] . Evangelio E., Rath N.P., Mirica L.M. Dalton transactions: An international journal of inorganic chemistry . 2012,第26期

机译：第一行过渡金属-叠氮化物络合物炔烃的环加成反应性研究：金属酶抑制剂合成的无机点击反应
4. Acid-base Characterization of Sodium Metal and Metal Oxide Loaded NaX Zeolites Preparedfrom the Decomposition of Supported Sodium Azide [C] . Eric J. Doskocil AIChE annual meeting . 2003

机译：负载叠氮化钠分解制备的金属钠和金属氧化物负载的NaX沸石的酸碱表征
5. The role of solvation on ion -molecule reactions: Elucidating mechanisms of heterogeneous atmospheric chemistry and the reactivity of metal -ligand complexes. [D] . Gilligan, John Joseph. 2000

机译：溶剂化在离子分子反应中的作用：阐明异质大气化学机制和金属-配体络合物的反应性。
6. Behaviour of Sera from Normal and Tumour Rats in the Iodine-Azide Reaction and in Polarographic Proteose Tests [O] . W. J. P. Neish 1954

机译：正常和肿瘤大鼠血清在叠氮化碘反应和极谱蛋白质测试中的行为
7. The Iodine-Azide Reaction. IV. Chain Length of the Carbon Disulphide Catalyzed Reaction. [O] . Niels Hofman-Bang, O. Hassel, M. Webb, 1950

机译：碘 - 叠氮化物反应。 IV。碳二硫化碳催化反应的链长。

Complexes of 2-Mercaptopyrimidines with Metals in Sodium Azide Solution.Investigation of Composition and Reactivity by Iodine-Azide Reaction

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