Aminophosphine Complex as a Catalyst Precursor in Suzuki Coupling Reactions?

Dongbin Zhao; Zhaofu Fei; Wee Han Ang

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Aminophosphine Complex as a Catalyst Precursor in Suzuki Coupling Reactions?

机译：氨基膦配合物作为铃木偶联反应中的催化剂前体吗？

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A palladium complex with an aminophosphine ligand has been prepared and investigated as a catalyst precursor in Suzuki coupling reactions in toluene. Nanoparticles composed of elemental palladium have been isolated from the reaction media and analyzed using transmission electroscopic microscope (TEM), which shows the essential catalysts palladium nanoparticles to have a size of ca. 3.0 nm.

机译：已经制备了具有氨基膦配体的钯配合物，并作为在甲苯中的Suzuki偶联反应中的催化剂前体进行了研究。从反应介质中分离出了由元素钯组成的纳米粒子，并使用透射电镜（TEM）进行了分析，结果表明基本催化剂钯纳米粒子的尺寸约为。 3.0纳米

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《Central European Journal of Chemistry》 |2008年第1期|共6页
作者
Dongbin Zhao; Zhaofu Fei; Wee Han Ang;
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正文语种 eng
中图分类化学工业;
关键词
Aminophosphosphine; Transition metal complex; X-ray; Catalysis; Nanoparticles;

机译：氨基膦;过渡金属配合物;X射线;催化;纳米粒子;

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专利

1. Aminophosphine Complex as a Catalyst Precursor in Suzuki Coupling Reactions? [J] . Dongbin Zhao, Zhaofu Fei, Wee Han Ang Central European Journal of Chemistry . 2008,第1期

机译：氨基膦配合物作为铃木偶联反应中的催化剂前体吗？
2. The first use of porphyrins as catalysts in cross-coupling reactions:a water-soluble palladium complex with a porphyrin ligand as an efficient catalyst precursor for the Suzuki-Miyaura reaction in aqueous media under aerobic conditions [J] . Ioannis D.Kostas, Athanassios G.Coutsolelos, Georgios Charalambidis Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2007,第38期

机译：卟啉在交叉偶合反应中的首次使用：带有卟啉配体的水溶性钯配合物作为有氧条件下水性介质中铃木-宫浦反应的有效催化剂前体
3. Bis-N,N-aminophosphine (PNP) crosslinked poly(p-tert-butyl styrene) particles: A new support for heterogeneous palladium catalysts for Suzuki coupling reactions [J] . Vece Vito, Szeto Kai C., Charlin Marc O., Catalysis Communications . 2019,第期

机译：双-N，N-氨基磷（PNP）交联聚（p-叔丁基苯乙烯）颗粒：用于铃木偶联反应的非均相钯催化剂的新载体
4. Bis(imino)pyridine Palladium(Ⅱ) complexes as Efficient Catalysts for Suzuki Cross-coupling Reaction in Neat Water [C] . The 12th Asian Pacific Confederation of Chemical Engineering Congress(第十二届亚太化工联盟大会暨化工展览会)论文集 . 2008

机译：双（亚氨基）吡啶钯（Ⅱ）配合物作为净水中铃木交叉偶联反应的有效催化剂
5. Size effect investigation of Palladium nanoparticles supported into Silica colloids as the catalyst for Suzuki cross coupling reaction. [D] . Sintara, Marsha. 2013

机译：载于二氧化硅胶体中的钯纳米粒子作为铃木交叉偶联反应催化剂的尺寸效应研究。
6. A Simple Hydrophilic Palladium(II) Complex as a Highly Efficient Catalyst for Room Temperature Aerobic Suzuki Coupling Reactions in Aqueous Media [O] . Mengping Guo, Shiwen Liu, Xiuling Zhou, 2014

机译：一种简单的亲水性钯（II）配合物作为水性介质中室温有氧铃木偶联反应的高效催化剂
7. Synthesis and catalytic applications of palladium N-heterocyclic carbene complexes as efficient pre-catalysts for Suzuki-Miyaura and Sonogashira coupling reactions [O] . Boubakri, Lamia, Yasar, S., Dorcet, V., 2017

机译：钯N-杂环卡宾配合物的合成及催化应用作为铃木-宫浦和Sonogashira偶联反应的有效前催化剂

Aminophosphine Complex as a Catalyst Precursor in Suzuki Coupling Reactions?

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