Alkylation of ambident indole anion in ionic liquids

Andris Zicmanis; Galina Vavilina; Svetlana Drozdova

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Alkylation of ambident indole anion in ionic liquids

机译：离子液体中环境吲哚阴离子的烷基化

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摘要

Alkylation of indole salts in different ionic liquids is reported.Ionic liquids increase the alkylation reaction rate of ambident indole anion and reduce the e?ects of counter ions and/or additives, the alkylation reaction rates being independent of the presence of small amounts of protic solvents or water.

机译：报道了在不同离子液体中吲哚盐的烷基化。离子液体提高了环境吲哚阴离子的烷基化反应速率并降低了抗衡离子和/或添加剂的作用，烷基化反应速率与少量质子的存在无关溶剂或水。

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《Central European Journal of Chemistry》 |2007年第1期|共13页
作者
Andris Zicmanis; Galina Vavilina; Svetlana Drozdova;
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正文语种 eng
中图分类化学;
关键词
Ionic liquids; ambident anion; alkylation reactions; indole;

机译：离子液体;环境阴离子;烷基化反应;吲哚;

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专利

1. Alkylation of ambident indole anion in ionic liquids [J] . Andris Zicmanis, Galina Vavilina, Svetlana Drozdova Central European Journal of Chemistry . 2007,第1期

机译：离子液体中环境吲哚阴离子的烷基化
2. A novel pyrrolidinium ionic liquid with l,l,2,2-tetrafluoro-2-(1,1,2,2-tetrafluoroethoxy)ethanesulfonate anion as a recyclable reaction medium and efficient catalyst for Friedel-Crafts alkylations of indoles with nitroalkenes [J] . Jin-Hong Lin, Cheng-Pan Zhang, Zhi-Qiang Zhu Journal of Fluorine Chemistry . 2009,第4期

机译：具有1,1,2,2-四氟-2-（1,1,2,2-四氟乙氧基）乙烷磺酸根阴离子作为可循环反应介质和吡咯烷鎓离子液体的新型催化剂，可有效催化吲哚与硝基烯烃的烷基化反应
3. Indole 3-alkylation/vinylation under catalysis of the guanidinium ionic liquids [J] . Rad-Moghadam K, Sharifi-Kiasaraie M Tetrahedron . 2009,第43期

机译：胍离子液体催化下的吲哚3-烷基化/乙烯基化
4. Triflic acid catalyzed continuous alkylation of isobutane and butene with ionic liquids as a promoter NHaifang LiDState Key Laboratory of Multiphase Complex System, Beijing Key Laboratory of Ionic Liquid Clean Process, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, 100190, China [C] . Guoying Zhao, Huiting Liu American Institute of Chemical Engineers Annual Meeting . 2012

机译：三氟酸催化异丁烷和丁烯的连续烷基化与离子液体作为启动子Nhaifang LID 州多相复合体系的关键实验室，北京中国科学院工艺工程研究所离子液体清洁工艺北京重点实验室，北京100190
5. Anion Basicity and Ionicity of Protic Ionic Liquids. [D] . Hasani, Mohammad. 2016

机译：质子离子液体的阴离子碱性和离子性。
6. Alkylation of Methyl Linoleate with Propene in Ionic Liquids in the Presence of Metal Salts [O] . Christian Silvio Pomelli, Tiziana Ghilardi, Cinzia Chiappe, 2015

机译：金属盐存在下离子液体中亚油酸甲酯与丙烯的烷基化
7. Supported Ionic Liquid H2PMo12O40-NMPIL@SiO2 as an Efficient Catalyst for Alkylation of Indoles with Epoxides or Alcohols under Mild Conditions [O] . Jin Tan, Dong Fang, Yu Lin Hu 2018

机译：支撑的离子液体H2PMO12O40-NMPIL @ SiO2作为在温和条件下用环氧化物或醇的吲哚烷基化的有效催化剂
8. HETEROGENEITY AS A FACTOR IN THE ALKYLATION OF AMBIDENT ANIONS:PHENOXIDE IONS1'2 [R] . Nathan Kornblum, Arnold P. Lurie 1958

机译：非均一性作为环境阴离子烷基化的因子：pHENOXIDE IONs1'2

Alkylation of ambident indole anion in ionic liquids

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