Mechanical properties and oxidation resistance of SiC_f/CVI-SiC composites with PIP-SiC interphase

摘要

SiC coatings were successfully synthesized on SiC fibers by precursor infiltration and pyrolysis (PIP) method using polycarbosilane (PCS) as precursor. The morphology of as-fabricated coatings was observed by SEM, and its structure was characterized by XRD and Raman spectrum. The SiC fiber reinforced chemical vapor infiltration SiC (SiC_f/CVI-SiC) composites with PIP-SiC coatings as interphase were fabricated. And, the effects of PIP-SiC interphase on mechanical properties of composites were investigated. The experimental results point out that the coating is smooth and there is little bridging between fibers. The coating is amorphous with SiC and carbon micro crystals. The flexural strength of composites with and without PIP-SiC interphase is 220 and 100 MPa, respectively. And the composites with PIP-SiC interphase obviously exhibit a toughened fracture behavior. The oxidation resistance of composites with PIP-SiC interphase is much better than that of composites with pyrolytic carbon (PyC) interphase.