The hindering function of phosphate on the grain growth behavior of nanosized zirconia powders calcined at high temperatures

摘要

Nanosized zirconia was prepared by a hydrothermal method using ZrOCl_2-8H20 and NaOH as raw materials. The obtained ZrO_2 powders were soaked in the phosphate solution with different concentrations. The as-prepared ZrO_2 powders and the powders treated with phosphate solution were calcined at different temperatures from 600 to 1000 °C. The samples were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM) and X-ray photoelectronic spectroscopy (XPS). The experimental results show that the untreated nanosized ZrO_2 grow and agglomerate to bulk when the ZrO_2 powders were calcined at high temperatures, while the ZrO_2 powders treated with phosphate solution grow slowly and remain nanosized crystal at the same calcination temperature. This phenomenon implied that phosphate treatment played an important role in inhibiting the crystal grain growth of ZrO_2. The possible inhibition mechanism could be explained to that P species on the surface of ZrO_2 can reduce the grain boundary mobility and prevent direct contact of ZrO_2 particles.