Synthesis and Magnetic Properties of a New Binuclear Copper(II) Complex with Naphthalato-Bridged Ligand~1

摘要

To utilized a bridged-ligand of 1,8-naphthalate dianion (NAPH) as building block by self-assembly technology, a new binuclear copper(II) compound [Cu2(μ-NAPH)2(DMF)4(H2O)2] ( ) has been constructed and structurally characterized by X-ray crystallography. Complex crystallizes in monoclinic, space group C2/c, with a = 17.822(9), b = 9.964(5), c = 23.194( 11) A and β = 102.385(5)°. Magnetic measurements confirm that presents a very weak antiferromagnetic interaction between the paramagnetic ions.