Manganese(II) 9-Molybdomanganate(IV),[Mn(H2O)4]3 centre dot [MnMo9O32] centre dot 2H2O:Synthesis,Thermal Analysis,IR Spectra,and Crystal Structure

摘要

The [Mn(H2O)4]3 centre dot [MnMo9O32] centre dot 2H2O complex was synthesized and studied by X-ray diffraction,thermogravimetry,powder X-ray diffraction,and IR spectroscopy.The crystals are trigonal:space group R32,a = 14.811(2) A,c= 14.232(2) A,V = 2703.7(8) A3,M = 1848.5,Z = 3,rho(calcd.) = 3.419 g/cm3.