Supramolecular Ensembles of Indium Thiocyanates with the [K(18C6)]~+ Complexes

摘要

Supramolecular ensembles containing cations [K(18C6)]~+ and anions [In(NCS)6]~(3-) were isolated from the InCl3-KNCS-18C6-CH3OH system. The associates were identified by the data of elemental analysis, IR spectra, and X-ray phase analysis. The X-ray diffraction analyses for [K(18C6)]2[In(MeOH)(NCS)5] and K[K(18C6)]2[In(NCS)6] showed the formation of heterometallic polymer fragments due to the bridging coordination of the NCS groups In-NCS-K.