Insights into the crystal structure of a polyoxomolybdate(VI) anion stabilized by ammonium cation: Inputs from X-ray diffraction and Hirshfeld surface analysis

摘要

A new polyoxomolybdate complex with chemical formula [NH2(CH3)(2)](4)[Mo8O26] (I) has been synthesized and structurally characterized. Single-crystal X-ray analysis of compound I reveals that the ammonium cation generates an intricate 2D supramolecular architecture (CIF file CCDC no. 1026577). The detail analyses of Hirschfeld surface and fingerprint plots gave a mode of non-covalent interactions in the title compound.