A Novel Zn(II) Complex Based on lH-1,2,3-Benzotriazol-1- Ylacetic Acid and 1H-1,2,3-Benzotriazole Ligands: Synthesis, Crystal Structure, and Photoluminescent Property

摘要

A novel complex formulated as [Zn(HBTA)2(L)2] · 2H2O (1), where HL = 1H-1,2,3-benzotria-zol-1-ylacetic acid, HBTA = 1H- 1,2,3-benzotriazole, has been synthesized and structurally characterized by single crystal X-ray diffraction. Complex I shows a mononuclear structure, which is assembled into ID chain via intermolecular π—π interactions and N—H—O hydrogen bonds. Different chains are linked by C—H—O hydrogen bonds into 2D layer. The photolurninescence property of the complex has been investigated.