Chiral Complexes of Pt with Amino Acids:Synthesis,Structure,Properties

摘要

Short review of syntheses of Pt(II)and Pt(IV)chiral complexes with amino acid ligands and their chemical and spectral studies(IR,electronic absorption,circular dichroism,and NMR spectra)is presented.X-ray diffraction data are reported for key chiral amino acid complexes of Pt and absolute configurations of asymmetric atoms of coordinated ligands are determined.The effect of the absolute configurations of asymmetric carbon,nitrogen,and sulfur atoms of the ligands on optical activity of complexes and on the rates of chemical and biochemical reactions is established.