A CONVENIENT METHOD FOR THE CONVERSION OF OXIMES TO KETONES AND ALDEHYDES USING THE JONES REAGENT SUPPORTED ON ALUMINUM SILICATE

JI-DONG LOU; FANG LIN; CHANGHE ZHANG

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A CONVENIENT METHOD FOR THE CONVERSION OF OXIMES TO KETONES AND ALDEHYDES USING THE JONES REAGENT SUPPORTED ON ALUMINUM SILICATE

机译：利用硅酸铝上支持的琼脂试剂将氧化酶转化为酮和醛的简便方法

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摘要

A convenient method for oxidative cleavage of oximes to the corresponding aldehydes and ketones with the Jones reagent supported on aluminum silicate at room temperature under heterogeneous conditions in the yields between 80 and 96% is described, which is an extension of application for the Jones reagent supported on aluminum silicate.

机译：描述了一种方便的方法，该方法用于在室温下在异质条件下用负载在硅酸铝上的Jones试剂将肟氧化裂解为相应的醛和酮，其收率在80％至96％之间，这是对负载的Jones试剂的应用扩展在硅酸铝上。

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来源
《Oxidation Communications》 |2013年第2期|共7页
作者
JI-DONG LOU; FANG LIN; CHANGHE ZHANG;
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正文语种 eng
中图分类化学;
关键词
aldehydes; aluminum silicate; the Jones reagent; ketones; oxidation; oximes.;

机译：醛;硅酸铝;琼斯试剂;酮;氧化;肟;

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专利

1. A CONVENIENT METHOD FOR THE CONVERSION OF OXIMES TO KETONES AND ALDEHYDES USING THE JONES REAGENT SUPPORTED ON ALUMINUM SILICATE [J] . JI-DONG LOU, FANG LIN, CHANGHE ZHANG Oxidation Communications . 2013,第2期

机译：利用硅酸铝上支持的琼脂试剂将氧化酶转化为酮和醛的简便方法
2. A facile procedure for the conversion of oximes to ketones and aldehydes by the use of jones reagent adsorbed on kieselguhr reagent [J] . Lou J.-D., Lin F., Lu X.L., Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry . 2012,第1a2期

机译：使用吸附在硅藻土试剂上的琼斯试剂将肟转化为酮和醛的简便方法
3. Jones reagent supported on aluminum silicate: A new reagent for oxidation of alcohols [J] . Lou JD, Li L, Vatanian N, Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry . 2008,第4期

机译：硅酸铝上支持的Jones试剂：一种用于醇氧化的新型试剂
4. GC/MS Studies on the Pentafluorobenzyl Oxime Derivatives of Long-chain Aliphatic Aldehydes and Ketones [C] . Viral V Brahmbhatt, Fong-Fu Hsu, David A Ford ASMS Conference on Mass Spectrometry and Allied Topics . 2007

机译：GC / MS研究长链脂族醛和酮的五氟苄基肟衍生物
5. Cyano-borrowing reaction: nickel-catalyzed direct conversion of cyanohydrins and aldehydes/ketones to β-cyano ketone [O] . Zhao-Feng Li, Qian Li, Li-Qing Ren, 2019

机译：氰化物借入反应：镍催化的氰醇和醛/酮直接转化为β-氰基酮
6. New methods and reagents in organic synthesis. 34. Diphenyl phosphorazidate (DPPA) as a 1,3-dipole. A simple, efficient conversion of akyl phenyl ketones to 2-phenylakanoic acids. [O] . NOBUTAKA KAWAI, TAKAYUKI SHIOIRI 1983

机译：有机合成中的新方法和试剂。 34.二苯基磷噻pid（DPPA）作为1,3-偶极物。一种简单，有效的α-烷基苯基酮转化为2-苯基己酸。

A CONVENIENT METHOD FOR THE CONVERSION OF OXIMES TO KETONES AND ALDEHYDES USING THE JONES REAGENT SUPPORTED ON ALUMINUM SILICATE

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