Does a tiny amount of dispersant make any change to refractory castable properties?

摘要

A growing demand for refractory castables with specific behaviors has given rise to a continuous technological evolution, mainly due to the broad knowledge of hydraulic binders available nowadays. The high alumina cements remain as the most important hydraulic binders for castables. Nevertheless, calcium aluminate bound castables still show a characteristic drop of strength at intermediate temperatures, which could also be affected by the castable chemical additive. Thus, this paper aims to highlight the influence of dispersants on the refractory castable properties with the firing temperature. It was noticed that the hydrates formed during the curing process of castable depends on the dispersing additive used. The FS60, a polycarboxylate ether, induced the AH_3 formation and its decomposition resulted in a more stable hydrate (AH), which increased the splitting strength with the thermal treatment temperature. At a high temperature, the CA_2 and CA_6 formation is also favored in the presence of this additive. However, it did not bring benefits to the castables creep behavior, resulting in a less tough structure.