Kinetics And Mechanism of Oxidation Of Cyclohexanone By Quinolinium Dichromate

SIMI DAS; MAHENDRA K. MAHANTI

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Kinetics And Mechanism of Oxidation Of Cyclohexanone By Quinolinium Dichromate

机译：重铬酸喹啉鎓氧化环己酮的动力学及机理

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Cyclohexanone is oxidised to adipic acid by quinolinium dichromate in aqueous acetic acid medium, in the presence of sulphuric acid. The reaction proceeded via the formation of enol. The slow step involved the reaction of the enol with the oxidant.

机译：在硫酸的存在下，在乙酸水溶液中，重铬酸喹啉鎓将重铬酸环己酮氧化为己二酸。反应通过形成烯醇进行。缓慢的步骤涉及烯醇与氧化剂的反应。

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《Oxidation Communications》 |2000年第4期|共5页
作者
SIMI DAS; MAHENDRA K. MAHANTI;
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正文语种 eng
中图分类化学;
关键词
mechanism; oxidation; cyclohexanone; quinolinium dichromate; sulphuric acid.;

机译：机理;氧化;环己酮;重铬酸喹啉鎓;硫酸;

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Kinetics And Mechanism of Oxidation Of Cyclohexanone By Quinolinium Dichromate

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