Effect of small-sized conductive filler on the properties of an epoxy composite for a bipolar plate in a PEMFC

摘要

This paper focused on using a conductive polymer composite (CPC) as a potential replacement for the conventional graphite bipolar plate used in polymer electrolyte membrane fuel cells (PEMFC). Based on the requirements established by the US Department of Energy (DOE), the in-plane electrical conductivity and flexural strength are required to be greater than l00S/cm and 25MPa, respectively. The high filler loading is needed to satisfy the high in-plane electrical conductivity. However, the high filler loading reduces the flexural strength and manufacturability of the composite. In this study, the composites were prepared by compounding using an internal mixer followed by compression moulding. The combination of 10 vol% carbon black (CB) as the second filler with synthetic graphite/epoxy (SG/EP) resulted in the following composite properties: 150 S/cm (in-plane conductivity), 55 S/cm (through-plane conductivity), and 38.8 MPa (flexural strength). Used as the second filler, the CB, which had a small-sized diameter, formed conductive networks that filled the voids between the SG and polymer matrix. The in-plane electrical conductivity and flexural strength of the CB/SG/EP composites at the optimum composition exceeded the requirement for bipolar plate applications.