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Correction: Nickel-catalyzed reductive coupling of alkyl halides with other electrophiles: concept and mechanistic considerations

机译:校正:卤代烷与其他亲电子试剂的镍催化还原偶联:概念和机理考虑

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摘要

On page 1416, due to an incorrect conclusion being drawn regarding the rate-determining steps, the authors regret that the following sentence in the original text: Therein the reductive elimination becomes rate-determining with an energy barrier of ~10 kcal mol1. Given the small energy difference between the possible mechanisms, subtle changes of the reaction parameters (e.g. concentrations) may favor one of the reaction pathways.
机译:在第1416页上,由于关于速率确定步骤的结论不正确,作者感到遗憾的是,原文中的以下句子:还原消除成为速率确定的,能量垒为〜10 kcal mol1。考虑到可能的机理之间的能量差很小,反应参数的细微变化(例如浓度)可能有利于反应途径之一。

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