SYNTHESIS AND X-RAY STRUCTURE OF [(ETA(5)-C(5)ME(5))TI(MU(3)-O)(3)(RH(COD))(3)] (COD=CYCLOOCTA-1,5-DIENE) - ORGANOMETALLIC APPROACH TO STRONG METAL-SUPPORT INTERACTION IN HETEROGENEOUS CATALYSIS

摘要

(eta(5)-C(5)Me(5))TiMe(3)] (1) reacts with [Rh(mu(2)-OH)(COD)](2) (2) to yield [(eta(5)-C(5)Me(5))Ti(mu(3)-O)(3){Rh(COD)}(3)] (3). The molecular structure of 3 shows that it can be compared to the cubane type structures M(4)X(4) in which the fourth X ligand position is absent. [References: 26