Formation and X-ray crystal structure determination of the novel triplatinum cluster [(Ph3P)Pt(mu-SiC12H8)](3) from reaction of silafluorene with (Ph3P)(2)Pt(eta(2)-C2H4)

Braddock-Wilking J.; Corey JY.; Dill K.; Rath NP.

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Formation and X-ray crystal structure determination of the novel triplatinum cluster [(Ph3P)Pt(mu-SiC12H8)](3) from reaction of silafluorene with (Ph3P)(2)Pt(eta(2)-C2H4)

机译：硅芴与（Ph3P）（2）Pt（eta（2）-C2H4）的反应形成新型三重金属簇[[Ph3P）Pt（mu-SiC12H8）]（3）的形成和X射线晶体结构测定

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Reaction of silafluorene (H2SiC12H8) with (Ph3P)(2)Pt(eta(2)-C2H4) in C6D6 (or C7D8) provided the trinuclear complex [(Ph3P)Pt(mu-SiC12H8)](3) (3). The structure of 3, which exhibits a nonplanar Pt3Si3 core, was confirmed by X-ray crystallography. [References: 24]

机译：硅芴（H2SiC12H8）与（Ph3P）（2）Pt（eta（2）-C2H4）在C6D6（或C7D8）中的反应提供了三核络合物[（Ph3P）Pt（mu-SiC12H8）]（3）（3）。通过X射线晶体学证实了具有非平面Pt 3 Si 3核的3的结构。 [参考：24]

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《Organometallics》 |2002年第25期|共3页
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Braddock-Wilking J.; Corey JY.; Dill K.; Rath NP.;
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正文语种 eng
中图分类有机化学;
关键词
Diplatinum complexes; Molecular-structure; Bridging disilene; Ligands; Dimers; Hydrosilanes; Silylene; Isomers;

机译：双铂配合物;分子结构;桥二烯;配体;二聚体;氢化硅烷;甲硅烷基;异构体;

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1. Formation and X-ray crystal structure determination of the novel triplatinum cluster [(Ph3P)Pt(mu-SiC12H8)](3) from reaction of silafluorene with (Ph3P)(2)Pt(eta(2)-C2H4) [J] . Braddock-Wilking J., Corey JY., Dill K., Organometallics . 2002,第25期

机译：硅芴与（Ph3P）（2）Pt（eta（2）-C2H4）的反应形成新型三重金属簇[[Ph3P）Pt（mu-SiC12H8）]（3）的形成和X射线晶体结构测定
2. Metal complexes of functionalized sulfur containing ligands, XV . Reactions of platinum(0) complexes with 1,2,4-trithiolanes, 1,2,4,5-tetrathianes, 1,2,3,5,6-pentathiepanes as well as thioketones. X-ray structure analysis of (Ph3P)(2)Pt(eta(2)-Ph2C = [J] . Weigand W., Robl C., Mloston G., Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 2000,第6期

机译：功能化的含硫配体XV的金属配合物。铂（0）配合物与1,2,4-三硫杂环戊烷，1,2,4,5-四硫杂环戊烷，1,2,3,5,6-五硫杂环戊烷以及硫酮的反应。（Ph3P）（2）Pt（eta（2）-Ph2C =的X射线结构分析
3. Reactivity of {(Ph3P)Pt[mu-eta(2)-H-SiH(Ar)]}(2) (Ar=2-isopropyl-6-methylphenyl) with phosphines. X-ray crystal structure of trans-{(dppe)Pt[mu-SiH(Ar)}(2) [J] . Braddock-Wilking J., Levchinsky Y., Rath NP. Inorganica Chimica Acta . 2002,第0期

机译：{（Ph3P）Ptμ-eta（2）-H-SiH（Ar）]}（2）（Ar = 2-异丙基-6-甲基苯基）与膦的反应性。反式{（dppe）Pt [mu-SiH（Ar）}（2）的X射线晶体结构
4. Selective Synthesis of Au_(20)Ag4M(SC2H4Ph)_(18) M=Pt or Pd Clusters and Determination of Their Geometric Structures by Single Crystal X-ray Diffraction Analysis [C] . Sakiat Hossain, Tasuku Ono, Mahiro Yoshioka 日本化学会春季年会講演予稿集 . 2018

机译：选择性合成AU_（20）Ag4m（SC2H4PH）_（18）M = Pt或Pd簇，并通过单晶X射线衍射分析测定它们的几何结构
5. ATOMIC AND ELECTRONIC STRUCTURE OF SUPPORTED MONOMETALLIC AND BIMETALLIC CLUSTERS (X-RAY ABSORPTION SPECTROSCOPY). [D] . SAMANT, MAHESH GOVIND. 1986

机译：支持的单金属和双金属团簇的原子和电子结构（X射线吸收光谱）。
6. Isolation of the Metalated Ylides Ph3P−C−CNM (M=Li Na K): Influence of the Metal Ion on the Structure and Bonding Situation [O] . Christopher Schwarz, Lennart T. Scharf, Thorsten Scherpf, -1

机译：金属化的叶立德Ph3P-C-CN M（M = LiNaK）的分离：金属离子对结构和键合情况的影响
7. Reaction of Diphenylgermane with (Ph3P)2Pt(h2-C2H4): Generation of Mono- and Dinuclear Complexes Containing Pt-Ge Bonds. X-ray Crystal Structure Determination of (Ph3P)Pt(m-h2-H-GePh2)2 [O] . -1

机译：二苯胺与（PH3P）2PT（H2-C2H4）的反应：含有PT-GE键的单核复合物的产生。 X射线晶体结构测定（pH3p）pt（m-h2-h-geph2） 2
8. Synthesis of Tetranuclear Mixed-Metal Clusters via the Reaction of Co(CO)4- with Closed Metal Carbonyl Trimers. Crystal and Molecular Structure of (Ph3P)2NCoRu3(CO)13 [R] . Steinhardt, P. C., Gladfelter, W. L., Harley, A. D., 1979

机译：Co（CO）4-与闭合金属羰基三聚体反应合成四核混合金属团簇。（ph3p）2NCoRu3（CO）13的晶体和分子结构

Formation and X-ray crystal structure determination of the novel triplatinum cluster [(Ph3P)Pt(mu-SiC12H8)](3) from reaction of silafluorene with (Ph3P)(2)Pt(eta(2)-C2H4)

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