Allyl/alkyne coupling reactions mediated by neutral ruthenium(II). Isolation and characterization of ruthenium(II) eta(3)-allyl eta(2)-alkyne complexes

Older CM.; Stryker JM.

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Allyl/alkyne coupling reactions mediated by neutral ruthenium(II). Isolation and characterization of ruthenium(II) eta(3)-allyl eta(2)-alkyne complexes

机译：中性钌（II）介导的烯丙基/炔烃偶联反应。钌（II）eta（3）-烯丙基eta（2）-炔烃配合物的分离和表征

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In contrast to the cyclization products obtained from allyl/alkyne coupling reactions in the isostructural cationic series, neutral complexes of the form (C5Me5)Ru(eta(3)-allyl)(eta(2)-alkyne) react to give acyclic eta(5)-pentadienyl complexes in high yield. [References: 55]

机译：与同构阳离子系列中从烯丙基/炔烃偶联反应获得的环化产物相反，（C5Me5）Ru（eta（3）-烯丙基）（eta（2）-炔烃）形式的中性络合物反应生成无环eta（ 5）-戊二烯基络合物，高产率。 [参考：55]

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《Organometallics 》 |2000年第14期| 共3页
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Older CM.; Stryker JM.;
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正文语种 eng
中图分类有机化学 ; 有机质材料 ;
关键词
Promoted carbonylative cycloaddition; Carbon bond activation; Alkyne complexes; Allyl; Reactivity; Ligands; lt; ru(c5me5)clgt; 4; Cyclizations; Molybdenum; Acetylenes;

机译：促进的羰基环加成;碳键活化;炔配合物;烯丙基;反应性;配体;ru（c5me5）cl 4;环化;钼;乙炔;

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1. Allyl/alkyne coupling reactions mediated by neutral ruthenium(II). Isolation and characterization of ruthenium(II) eta(3)-allyl eta(2)-alkyne complexes [J] . Older CM., Stryker JM. Organometallics . 2000 ,第14期

机译：中性钌（II）介导的烯丙基/炔烃偶联反应。钌（II）eta（3）-烯丙基eta（2）-炔烃配合物的分离和表征
2. Unprecedented Coordination Modes and Demetalation Pathways for Unbridged Polyenyl Ligands.Ruthenium eta~1,eta~4-Cycloheptadienyl Complexes from Allyl/Alkyne Cycloaddition [J] . Christina M.Older, Robert McDonald, Jeffrey M.Stryker Journal of the American Chemical Society . 2005 ,第41期

机译：未桥联的多烯配体的前所未有的配位方式和脱金属途径。烯丙基/炔环加成反应中的钌eta〜1，eta〜4-环庚二烯基络合物
3. Facile formation of chloro - eta(3)-allyl complexes by reaction of vinyldiazoacetates and ruthenium(II) arene complexes [J] . Nishiyama H., Konno M., Aoki K. Organometallics . 2002 ,第12期

机译：通过乙烯基重氮乙酸酯和钌（II）芳烃络合物的反应轻松形成氯-eta（3）-烯丙基络合物
4. Reactions of Dinuclear Ruthenium Bridging Imido Complexes with Alkynes [C] . Shin Takemoto, Yusaku Masuhara, Takahiro Ito Symposium on Organometallic Chemistry . 2007

机译：二核钌桥接与炔烃络合物的反应
5. I. Chromium(III)-catalyzed carbometalation of alkynes. II. Chromium(III)-catalyzed synthesis of allenes via a syn-carbometalation/syn-elimination sequence. III. Palladium(0)-catalyzed synthesis of ene-allenes via cross-coupling reactions with alkenyl trifluoroborates. [D] . Sommers, Erin McGeehan. 2006

机译：I.铬（III）催化炔烃的碳金属化。二。铬（III）通过顺碳共金属/顺消除序列催化的丙二烯合成。三，钯（0）通过烯基三氟硼酸酯的交叉偶联反应催化烯-烯的合成。
6. Synthesis of unsymmetrical alkyl acetals via addition of primary alcohols to allyl ethers mediated by ruthenium complexes [O] . Stanisław Krompiec, Mateusz Penkala, Ewelina Kowalska, -1

机译：通过将伯醇加到钌络合物介导的烯丙基醚中合成不对称烷基缩醛
7. Mechanism Investigations of the Endo Cycloisomerization of Alkynols through Isolation and Characterization of Ruthenium Complexes from the Reactions of Alkynes with a Ruthenium Complex [O] . Liu Pei Nian, Wen Ting Bin, Ju Kun Dong, 2011

机译：从炔烃与钌配合物的反应中分离和表征钌配合物，对炔醇的内酯环内异构化机理的研究
8. Study of Fundamental Reaction Pathways for Transition Metal Alkyl Complexes. I. The Reaction of a Nickel Methyl Complex with Alkynes. II. The Mechanism of Aldehyde Formation in the Reaction of a Molybdenum Hydride with Molybdenum [R] . Huggins, J. M. 1980

机译：过渡金属烷基配合物的基本反应途径研究。 I.镍甲基配合物与炔烃的反应。 II。氢化钼与钼反应生成醛的机理

Allyl/alkyne coupling reactions mediated by neutral ruthenium(II). Isolation and characterization of ruthenium(II) eta(3)-allyl eta(2)-alkyne complexes

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