New Router to Organodecaborane Polymers via Ruthenium-Catalyzed Ring-Opening Metalthesis Polymerization

Xiaolan Wei; Patrick J.Carroll; Larry G.Sneddon

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New Router to Organodecaborane Polymers via Ruthenium-Catalyzed Ring-Opening Metalthesis Polymerization

机译：通过钌催化的开环金属复分解聚合制得有机硼烷聚合物的新方法

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The compounds 6-(norbornenyl)decaborane and 6-(cyclooctenyl)decaborane were synthesized in >95% yields by the titanium-catalyzed reaction of norbornadiene and cyclooctadiene with decaborane.Ring-opening metathesis polymerization of these monomers employing either first-or second-generation Grubbs catalysts produced the corresponding poly(6-(norbornenyl)decaborane)and poly(6-(cyclooctenyl)decaborane)polymers with M_n>30 kDa and polydispersities between 1.1 and 1.8.

机译：通过降冰片二烯和环辛二烯与十硼烷的钛催化反应，合成> 6-（降冰片烯基）十硼烷和6-（环辛烯基）十硼烷的产率> 95％。这些单体的开环易位聚合采用第一或第二新一代的Grubbs催化剂生产了相应的聚（6-（降冰片烯基）十硼烷）和聚（6-（环辛烯基）十硼烷）聚合物，M_n> 30 kDa，多分散度在1.1至1.8之间。

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《Organometallics》 |2004年第2期|共3页
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Xiaolan Wei; Patrick J.Carroll; Larry G.Sneddon;
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1. New Router to Organodecaborane Polymers via Ruthenium-Catalyzed Ring-Opening Metalthesis Polymerization [J] . Xiaolan Wei, Patrick J.Carroll, Larry G.Sneddon Organometallics . 2004,第2期

机译：通过钌催化的开环金属复分解聚合制得有机硼烷聚合物的新方法
2. Synthesis of tri-arm star di-block co-polymer containing poly(tetrahydrofuran-b-methyl methacrylate) arms via combination of cationic ring-opening polymerization and photosensitized free radical polymerization routes [J] . GURKAN HIZAL, DOLUNAY SAKAR, UMIT TUNCA Designed Monomers and Polymers: An International Journal on Monomer and Macromolecular Synthesis . 2005,第6期

机译：通过阳离子开环聚合和光敏自由基聚合途径合成含聚四氢呋喃-b-甲基丙烯酸甲酯的三臂星形二嵌段共聚物
3. Transition metal-mediated polymerization as a route to transition metal-based polymers: mechanistic insights into the ring-opening polymerization of [1]-silaferrocenophanes [J] . K. Temple, F. Jakle, A. J. Lough, Polymer Preprints . 2000,第1期

机译：过渡金属介导的聚合，作为过渡金属基聚合物的途径：[1] -silaferrocenophanes开环聚合的机械机理
4. Ruthenium-Catalyzed Cascade Ring-Opening Polymerization/Hydroboration for the Synthesis of Low Cross-linking Poly (6-norbornenyldecaborane) and Its Thermal Property [C] . Jun-peng LI, Han YANG, Yun LIANG International Conference on Material Science and Engineering . 2014

机译：钌催化的级联开环聚合/水合用于合成低交联聚（6- NorbornenyldeCaborane）及其热性能
5. Ring-opening polymerization of [1]metallocenophanes: A route to organometallic polymeric micelles, ionomeric poly(ferrocenes) and other systems of interest. [D] . Peckham, Timothy James. 1998

机译：[1]茂金属的开环聚合：通往有机金属聚合物胶束，离聚物聚二茂铁和其他目标体系的途径。
6. Organocatalyzed ring-opening copolymerization of α-bromo-γ-butyrolactone with ε-caprolactone for the synthesis of functional aliphatic polyesters – pre-polymers for graft copolymerization [O] . Chen Gao, Chi-Hui Tsou, Chun-Yan Zeng, 2018

机译：α-溴-γ-丁内酯与ε-己内酯的有机催化开环共聚反应以合成功能性脂肪族聚酯-接枝共聚的预聚物
7. Tuning the properties of α,ω-bis(trialkoxysilyl) telechelic copolyolefins from ruthenium-catalyzed chain-transfer ring-opening metathesis polymerization (ROMP) [O] . Michel, Xiaolu, Fouquay, Stéphane, Michaud, Guillaume, 2017

机译：钌催化的链转移开环复分解聚合（ROMP）调节α，ω-双（三烷氧基甲硅烷基）远螯共聚烯烃的性能
8. Ring-Opening Polymerization of Strained Cyclotetrasilanes as a New Route Towards Well Defined Polysilylenes. [R] . Cypryk, M., Chrusciel, J., Fossum, E., 1994

机译：应变环四硅烷的开环聚合作为定义明确的聚硅烯的新途径。

New Router to Organodecaborane Polymers via Ruthenium-Catalyzed Ring-Opening Metalthesis Polymerization

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