Application of palladium-catalyzed allylic arylation to the synthesis of a (+/-)-7-deoxypancratistatin analogue

Shukla KH; Boehmler DJ; Bogacyzk S; Duvall BR; Peterson WA; McElroy WT; DeShong P

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Application of palladium-catalyzed allylic arylation to the synthesis of a (+/-)-7-deoxypancratistatin analogue

机译：钯催化的烯丙基芳基化在合成（+/-）-7-脱氧潘克拉斯汀类似物中的应用

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摘要

Palladium-catalyzed coupling of an aryl siloxane and an allylic carbonate proceeded in good yield to give an adduct that was converted to an analogue of (+/-)-7-deoxypancratistatin.

机译：钯催化的芳基硅氧烷和烯丙基碳酸酯的偶联以良好的收率进行，得到加成物，其被转化为（+/-）-7-脱氧潘克拉汀的类似物。

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《Organic letters》 |2006年第19期|共4页
作者
Shukla KH; Boehmler DJ; Bogacyzk S; Duvall BR; Peterson WA; McElroy WT; DeShong P;
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正文语种 eng
中图分类有机化学;
关键词
ANTITUMOR ALKALOID (+)-PANCRATISTATIN; BETA-AZIDONATION REACTION; AMARYLLIDACEAE CONSTITUENTS; NARCICLASINE ALKALOIDS; ANTINEOPLASTIC AGENTS; D-GLUCOSE; PANCRATISTATIN; DERIVATIVES; 7-DEOXYPANCRATISTATIN; (+)-NARCICLASINE;

机译：抗碱性生物碱（+）-胰蛋白酶;BET叠氮反应;芳樟科成分;纳卡西碱碱;抗肿瘤剂;D-葡萄糖;胰肽素;衍生物;7-脱氧泛环素;（+）-纳卡西汀;

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1. Application of palladium-catalyzed allylic arylation to the synthesis of a (+/-)-7-deoxypancratistatin analogue [J] . Shukla KH, Boehmler DJ, Bogacyzk S, Organic letters . 2006,第19期

机译：钯催化的烯丙基芳基化在合成（+/-）-7-脱氧潘克拉斯汀类似物中的应用
2. Application of palladium-catalyzed allylic arylation to the synthesis of a (+/-)-7-deoxypancratistatin analogue [J] . Shukla KH, Boehmler DJ, Bogacyzk S, Organic letters . 2006,第19期

机译：钯催化的烯丙基芳基化在合成（+/-）-7-脱氧潘克拉斯汀类似物中的应用
3. The first example of palladium-catalyzed cascade amidine arylation-intramolecular ester amidation for the synthesis of hypoxanthines: application to the synthesis of 8-azanebularine analogues [J] . Wu Yang, Haoran Ma, Qian Yang, Organic & biomolecular chemistry . 2017,第2期

机译：钯催化级联am芳基芳基化-分子内酯酰胺化合成次黄嘌呤的第一个实例：在合成8-azanebularine类似物中的应用
4. Synthesis of Helicenes Utilizing Palladium-Catalyzed Double C-H Arylation Reaction [C] . Ken Kamikawa, Ippei Takemoto, Shin Takemoto Symposium on Organometallic Chemistry . 2007

机译：利用钯催化的双C-H芳基化反应的螺旋合成
5. Palladium-catalyzed allylic-arylation: Mechanistic studies and application to the total synthesis of (+/-)-7-deoxypancratistatin derivatives. [D] . Shukla, Krupa H. 2009

机译：钯催化的烯丙基芳基化：机理研究及其在（+/-）-7-脱氧潘克拉斯汀衍生物的全合成中的应用。
6. Palladium-Catalyzed C–H Arylation of αβ-Unsaturated Imines: Catalyst-Controlled Synthesis of Enamine and Allylic Amine Derivatives [O] . Minyan Li, María González-Esguevillas, Dr. Simon Berritt, -1

机译：钯催化αβ-不饱和亚胺的CHH芳基化反应：烯胺和烯丙胺衍生物的催化剂控制合成
7. Application of Palladium-Catalyzed Allylic Arylation to the Synthesis of a ()-7-Deoxypancratistatin Analogue [O] . -1

机译：钯催化的烯丙基芳基合成A（）-7-脱氧曲苷素类似物的应用

Application of palladium-catalyzed allylic arylation to the synthesis of a (+/-)-7-deoxypancratistatin analogue

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