Mono- and Binuclear Cyclopalladium 1-Phenylpyrazole Complexes with Chelating Ligands

摘要

Existence of long-living exited states and reversible character of outer sphere transitions of electrons in cyclometallic complexes of platinum group metals defines perspective of their application as components of molecular-organized light sensitive systems[1].Presence in such complexes together with metallocomplex{M(C^N)}fragment of chelating(N^N)ligands extends possibility of modification of their optical and electrochemical properties[2].