Solvent Effect on Metal Oxidation Rates in Aprotic Media

摘要

A correlation between the rates of oxidation of metals with organometallic chlorides in aprotic media and the physicochemical properties of the solvents was established.An equation fitting the experimental data for ten reaction series was suggested.The kinetic parameters of oxidation of cadmium with diphenyl-bismuth chloride in aprotic media,calculated with the correlation equations,coincide with the experimental data.