Oxidation of Magnesium,Indium,and Thallium with Molybdenum and Cobalt Binuclear Carbonyl Complexes in Polar Solvents

摘要

Oxidation of magnesium and thallium with bis(eta~5-cyclopentadienyltricarbonylmolybdenum) in dimethyl sulfoxide and of indium with octacarbonyldicobalt in tetrahydrofuran was studied.The formal-kinetics relationships of the processes were revealed,and the intermediate and final products were identified.The apparent equilibrium constants,enthalpies and entropies of adsorption of reactants on the metal surface,and rate constants and activation energies of the reactions were determined.The reaction scheme was suggested.