Pt(II) and Pd(II) Complexes with (2-Bromo-1 -phenylvinyl)diphenylphosphine and Tris(Z-styryl)phosphine

摘要

Methods were developed for selective synthesis of geometric isomers of Pt(II) and Pd(II) complexes with (2-bromo-l-phenylvinyl)diphenylphosphine and tris(Z-styryl)phosphine.Transformations of unsaturated organophosphorus compounds in the metal coordination sphere [1-3] and catalytic processes involving transition metaphos-phine complexes [4-6] are new fields of hetero-organic chemistry.Therefore,synthesis of new complexes containing unsaturated organophosphorus ligands in the coordination sphere is of interest.