The role of oxygen in the reaction of ferrocene with benzoyl peroxide

Murinov Yu. I.; Grabovskiy S. A.; Kuramshina A. R.; Antipin A. V.; Kabalnova N. N.

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The role of oxygen in the reaction of ferrocene with benzoyl peroxide

机译：氧在二茂铁与过氧化苯甲酰反应中的作用

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Participation of molecular oxygen in the reaction of ferrocene with benzoyl peroxide in various solvents is demonstrated. The stoichiometry of the reaction ferrocene: oxygen is determined at 2: 1. Based on NMR, IR spectroscopy, iodometry, and elemental analysis of the product the formation of [mu-(peroxy-O:O')]-diferrocenium benzoate is suggested.

机译：分子氧参与了二茂铁与过氧化苯甲酰在各种溶剂中的反应。二茂铁：氧气的化学计量比为2：1。基于NMR，IR光谱，碘量法和产物的元素分析，建议形成[mu-（peroxy-O：O'）]-二茂铁苯甲酸盐。

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《Russian Journal of General Chemistry》 |2015年第1期|共3页
作者
Murinov Yu. I.; Grabovskiy S. A.; Kuramshina A. R.; Antipin A. V.; Kabalnova N. N.;
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正文语种 eng
中图分类化学;
关键词
ferrocene; oxidation; peroxides; kinetics;

机译：二茂铁;氧化;过氧化物;动力学;

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1. The role of oxygen in the reaction of ferrocene with benzoyl peroxide [J] . Murinov Yu. I., Grabovskiy S. A., Kuramshina A. R., Russian Journal of General Chemistry . 2015,第1期

机译：氧在二茂铁与过氧化苯甲酰反应中的作用
2. Multiple Roles of Superoxide on Oxygen Reduction Reaction in Li+-Containing Nonaqueous Electrolyte: Contribution to the Formation of Oxide as Well as Peroxide [J] . Dilimon V. S., Lee Dong-Gyu, Yim Sung-Dae, The journal of physical chemistry, C. Nanomaterials and interfaces . 2015,第7期

机译：超氧化物对含Li +的非水电解质中氧还原反应的多重作用：对氧化物和过氧化物形成的贡献
3. On the role of the surfactant aliquate (R) 336 on, the kinetics of oxygen reduction reaction and on the rate of hydrogen peroxide electro synthesis [J] . de Oliveira B, Bertazzoli R Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry . 2007,第1a2期

机译：关于表面活性剂aliquate（R）336的作用，氧还原反应的动力学以及过氧化氢的电合成速率
4. Evolutions on isothermal reaction of benzoyl peroxide by DSC and TAM Ⅲ [C] . Chen-Wei Chiu, Sun-Ju Shen, Tung-Feng Hsieh North American Thermal Analysis Society conference . 2011

机译：DSC和TAMⅢ对过氧化苯甲酰等温反应的演变
5. Suspension polymerization of methyl methacrylate initiated by benzoyl peroxide: Kinetics of initiation and modelling of polymerization reactions. [D] . Shetty, Somnath S. 1993

机译：过氧化苯甲酰引发的甲基丙烯酸甲酯的悬浮聚合：引发动力学和聚合反应模型。
6. Hydrogen peroxide plays a key role in the oxidation reaction of myoglobin by molecular oxygen. A computer simulation. [O] . T Wazawa, A Matsuoka, G Tajima, 1992

机译：过氧化氢在肌红蛋白被分子氧氧化反应中起关键作用。计算机模拟。
7. Lipid peroxidation in cotton:Xanthomonasinteractions and the role of lipoxygenases during the hypersensitive reaction [O] . A. Jalloul, J. L. Montillet, K. Assigbetsé, 2002

机译：棉花中的脂质过氧化：Xanthomonas粉碎和脂氧基酶在过敏反应期间的作用
8. Reactions of Mo2(OR)6 (M triple bond M) Compounds (R = Pr(i) and Bu(t) with Benzoyl Peroxide. [R] . Chisholm, M. H., Huffman, J. C., Kirkpatrick, C. C. 1982

机译：mo2（OR）6（m三键m）化合物（R = pr（i）和Bu（t））与过氧化苯甲酰的反应。

The role of oxygen in the reaction of ferrocene with benzoyl peroxide

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