Reaction of 4-aryl-2-methylbut-3-yn-2-ols with thiourea as a new approach to the synthesis of 4-arylmethylidene-5,5-dimethyl-4,5-dihydrothiazole-2-amines

D. S. Baranov; V. I. Mamatyuk; Yu. V. Gatilov

首页> 外文期刊>Russian Chemical Bulletin >Reaction of 4-aryl-2-methylbut-3-yn-2-ols with thiourea as a new approach to the synthesis of 4-arylmethylidene-5,5-dimethyl-4,5-dihydrothiazole-2-amines

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Reaction of 4-aryl-2-methylbut-3-yn-2-ols with thiourea as a new approach to the synthesis of 4-arylmethylidene-5,5-dimethyl-4,5-dihydrothiazole-2-amines

机译：4-芳基-2-甲基丁-3-yn-2-醇与硫脲的反应是合成4-芳基亚甲基-5,5-二甲基-4,5-二氢噻唑-2-胺的新方法

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摘要

A reaction of thiourea with 4-aryl-2-methylbut-3-yn-2-ols in refluxing pyridine led to the synthesis of 4-arylmethylidene-5,5-dimethyl-4,5-dihydrothiazole-2-amines.

机译：硫脲与4-芳基-2-甲基丁-3-yn-2-醇在回流吡啶中的反应导致合成4-芳基亚甲基-5，5-二甲基-4，5-二氢噻唑-2-胺。

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《Russian Chemical Bulletin》 |2012年第8期|共5页
作者
D. S. Baranov; V. I. Mamatyuk; Yu. V. Gatilov;
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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
alkynes; heterocyclization; thiourea; 2-thiazolines;

机译：炔烃;杂环化;硫脲;2-噻唑啉;

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1. Reaction of 4-aryl-2-methylbut-3-yn-2-ols with thiourea as a new approach to the synthesis of 4-arylmethylidene-5,5-dimethyl-4,5-dihydrothiazole-2-amines [J] . D. S. Baranov, V. I. Mamatyuk, Yu. V. Gatilov Russian Chemical Bulletin . 2012,第8期

机译：4-芳基-2-甲基丁-3-yn-2-醇与硫脲的反应是合成4-芳基亚甲基-5,5-二甲基-4,5-二氢噻唑-2-胺的新方法
2. Amine Thiourea Catalysed Double Michael Reaction: An Approach for the Asymmetric Synthesis of Spiro[pyrazolone-4,3 '-tetrahy-drothiophenes] [J] . Meninno Sara, Overgaard Jacob, Lattanzi Alessandra Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2017,第7期

机译：胺硫脲催化双迈克尔反应：螺螺（Pyrozolone-4,3'-roethy-Drothiophenes）的不对称合成方法。
3. The Quinine Thiourea-Catalyzed Asymmetric Strecker Reaction: An Approach for the Synthesis of 3-Aminooxindoles [J] . Dong Wang, Jinyan Liang, Jingchao Feng Advanced synthesis & catalysis . 2013,第2a3期

机译：奎宁硫脲催化的不对称Strecker反应：合成3-Aminooxindoles的一种方法。
4. Synthesis and characterization of thiourea complex encapsulated into functionalized-MCM41 and their catalytic activities for oxidation reaction [C] . Ahmad A., Kassim K., Rasid H.M. 2012 IEEE Colloquium on Humanities, Science and Engineering Research . 2012

机译：封装在功能化-MCM41中的硫脲复合物的合成，表征及其对氧化反应的催化活性
5. I. Enantioselective total synthesis of quinine and quinidine. II. Thiourea-catalyzed enantioselective C-C bond-forming reactions. a. Catalytic asymmetric N-acyliminium ion cyclizations. b. Catalytic asymmetric aza-Baylis-Hillman reactions [D] . Raheem, Izzat Tiedje 2008

机译：I.奎宁和奎尼丁的对映选择性全合成。二。硫脲催化的对映选择性C-C键形成反应。一个。催化不对称N-酰亚胺离子环化。 b。催化不对称氮杂-Baylis-Hillman反应
6. Facile regiodivergent synthesis of spiro pyrrole-substituted pseudothiohydantoins and thiohydantoins via reaction of e-fused 1H-pyrrole-23-diones with thiourea [O] . Aleksandr I Kobelev, Nikita A Tretyakov, Ekaterina E Stepanova, 2019

机译：通过e稠合的1H-吡咯-23-二酮与硫脲的反应容易地合成螺吡咯取代的假硫代乙内酰脲和硫代乙内酰脲
7. The quinine thiourea-catalyzed asymmetric Strecker reaction : an approach for the synthesis of 3-aminooxindoles [O] . Wang D, Liang J, Feng J, 2013

机译：奎宁硫脲催化的不对称Strecker反应：合成3-氨基羟吲哚的一种方法
8. Sidewall Covalent Functionalization of Single Wall Carbon Nanotubes through C-N Bond Forming Reactions of Fluoronanotubes with Urea, Guanidine and Thiourea (Preprint) [R] . Pulikkathara, M. X. , Khabashesku, V. N. 2007

机译：单壁碳纳米管的侧壁共价功能化通过C-N键形成氟脲与尿素，胍和硫脲的反应（预印本）

Reaction of 4-aryl-2-methylbut-3-yn-2-ols with thiourea as a new approach to the synthesis of 4-arylmethylidene-5,5-dimethyl-4,5-dihydrothiazole-2-amines

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