Synthesis of methyl furan-2-carboxylate and dimethyl furan-2,5-dicarboxylate by copper-catalyzed reactions of furans with CC14 and MeOH

R. I. Khusnutdinov; A. R. Bayguzina; R. R. Mukminov

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Synthesis of methyl furan-2-carboxylate and dimethyl furan-2,5-dicarboxylate by copper-catalyzed reactions of furans with CC14 and MeOH

机译：呋喃与CC14和MeOH的铜催化反应合成呋喃-2-羧酸甲酯和呋喃-2,5-二羧酸二甲酯

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摘要

Methyl furan-2-carboxylate and dimethyl furan-2,5-dicarboxylate were obtained in high yields by copper-catalyzed reactions of furan, furfural, 2-acetylfuran, and furan-2-carboxylic acid with CCl4 and MeOH.

机译：通过呋喃，糠醛，2-乙酰基呋喃和呋喃-2-羧酸与CCl4和MeOH的铜催化反应，可以高收率获得呋喃-2-羧酸甲酯和呋喃-2,5-二羧酸二甲酯。

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《Russian Chemical Bulletin 》 |2013年第1期| 共5页
作者
R. I. Khusnutdinov; A. R. Bayguzina; R. R. Mukminov;
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正文语种 eng
中图分类化学 ;
关键词
metal complex catalysis; copper compounds; methyl furan-2-carboxylate; dimethyl furan-2; 5-dicarboxylate; alkylation; alcoholysis.;

机译：金属配合物催化;铜化合物;呋喃-2-羧酸甲酯;呋喃-2二甲基;5-二羧酸酯;烷基化;醇解;

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1. Synthesis of methyl furan-2-carboxylate and dimethyl furan-2,5-dicarboxylate by copper-catalyzed reactions of furans with CC14 and MeOH [J] . R. I. Khusnutdinov, A. R. Bayguzina, R. R. Mukminov Russian Chemical Bulletin . 2013 ,第1期

机译：呋喃与CC14和MeOH的铜催化反应合成呋喃-2-羧酸甲酯和呋喃-2,5-二羧酸二甲酯
2. Synthesis and Structure of (3R,3aR,4S,4aR,5S,9aR)-4-Hydroxy-4a,5-Dimethyl-3-{[4-(4-Fluorophenyl)-Piperazino]Methyl}-3a,4,4a,5,6,7,9,9a-Octahydronaphtho [2,3-b]Furan-2(3H)-One [J] . Klochkov S. G., Romanova A. A., Ananev I. V., Chemistry of Natural Compounds . 2018 ,第6期

机译：（3r，3ar，4s，4ar，5s，9ar）-4-羟基-4a，5-二甲基-3 - {[4-（4-氟苯基）-piperazino]甲基} -3a，4,4a的合成和结构，5,6,7,9,9a-odahydronaphtho [2,3-b] furan-2（3h） - 酮
3. Synthesis and Structure of (3R,3aR,4S,4aR,5S,9aR)-4-Hydroxy-4a,5-Dimethyl-3-{[4-(4-Fluorophenyl)-Piperazino]Methyl}-3a,4,4a,5,6,7,9,9a-Octahydronaphtho [2,3-b]Furan-2(3H)-One [J] . Klochkov S. G., Romanova A. A., Ananev I. V., Chemistry of Natural Compounds . 2018 ,第6期

机译：（3r，3ar，4s，4ar，5s，9ar）-4-羟基-4a，5-二甲基-3 - {[4-（4-氟苯基）-piperazino]甲基} -3a，4,4a的合成和结构，5,6,7,9,9a-odahydronaphtho [2,3-b] furan-2（3h） - 酮
4. Synthesis of α-Fluoroimines from Copper-Catalyzed Reactions of Diarylacetylenes and N-Fluorobenzenesulfonimide [C] . Shu Jan Yip, Tetsushi Yoshidomi, Kei Murakami 日本化学会春季年会講演予稿集 . 2018

机译：二芳基乙烯基铜催化反应的α-氟杂质的合成，N-氟苯磺酰胺
5. The synthesis of the A/B ring system of the arisugacins and territrems and studies on the intramolecular Diels-Alder reactions of furans and progress toward the total synthesis of the arisugacins and territrems . [D] . Min, Sun-Joon. 2005

机译：Arisugacins和Territrems的A / B环体系的合成及其呋喃分子内Diels-Alder反应的研究以及Arisugacins和Territrems的合成。
6. (3R,4R,5S)-4-Hydroxy-3-methyl-5-[(2S,3R)-3-methylpent-4-en-2-yl]-4,5-dihydrofuran-2(3H)-one [O] . Annika Gille, Markus Schürmann, Hans Preut, 2016

机译：（3R，4R，5S）-4-羟基-3-甲基-5-[（2S，3R）-3-甲基戊-4-烯-2-基] -4,5-二氢呋喃-2（3H）-
7. Concurrent formation of furan-2,5- and furan-2,4-dicarboxylic acid: unexpected aspects of the Henkel reaction [O] . Thiyagarajan, S., Pukin, A., van Haveren, J., 2013

机译：呋喃-2,5-和呋喃-2,4-二羧酸的竞争者形成：汉高反应的意外方面

Synthesis of methyl furan-2-carboxylate and dimethyl furan-2,5-dicarboxylate by copper-catalyzed reactions of furans with CC14 and MeOH

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