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An improved method for the measurement of lifetimes of long-lived coherences in NMR

机译:一种用于测量NMR中长寿命相干寿命的改进方法

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摘要

Rotating frame zero quantum or long-lived coherences among singlet-triplet states in two weakly coupled protons are known to have longer lifetimes than Zeeman magnetization. The usual method for measuring these lifetimes involves fitting a damped oscillatory function, which is lengthy and ineffective for various NMR studies and in turn restricts its usefulness. Here, we introduce a new robust strategy to overcome this problem.
机译:已知在两个弱耦合质子中的单重态-三重态之间旋转的零量子相干或长寿命相干的寿命比塞曼磁化寿命更长。测量这些寿命的常用方法包括安装阻尼振荡函数,该函数冗长且对各种NMR研究无效,进而限制了其实用性。在这里,我们介绍了一种新的可靠策略来克服此问题。

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