Microwave-assisted synthesis of novel julolidinyl-based nonlinear optical chromophores with enhanced electro-optic activityMicrowave-assisted synthesis of novel julolidinyl-based nonlinear optical chromophores with enhanced electro-optic activity

摘要

Under microwave (MW) irradiation at a proper temperature, three chromophores (A, B, C) with julolidinyl-based donors and TCF or CF3-Ph-TCF acceptors have been synthesized in high overall yields compared with the conventional heating method. The introduction of a MW heating approach in the synthesis of these chromophores proved to markedly shorten reaction times, reduce by-products and increase the efficiency. The solvatochromic behavior and cyclic voltammetry (CV) measurements suggested that chromophores B and C with stronger acceptors can be more easily polarized with respect to chromophore A. The solvent dependence of the relevant theoretical parameters including dipole moment (mu), first-order polarizability (alpha), hyperpolarizability (beta) and bond-length alternation (BLA) of all chromophores were also studied by DFT calculations. All these chromophores showed good thermal stability and large b values. In an electro-optic (EO) activities test, the guest-host poled polymer A/APC exhibited the highest EO coefficient (r(33)) of 192 pm V-1 at 1.31 mu m. The MW-assisted syntheses and systematic analyses afforded a rational design for NLO chromophores, and provided a new method to optimize the structures of the chromophores to achieve higher r(33) values.