Rh(III)-catalyzed tandem oxidative olefination-cyclization of aryl sulfonamides

Ding Qiuping; Liu Tong; Zheng Qiang; Zhang Yadong; Long Ling; Peng Yiyuan

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Rh(III)-catalyzed tandem oxidative olefination-cyclization of aryl sulfonamides

机译：Rh（III）催化的芳基磺酰胺串联氧化烯化环化反应

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摘要

An efficient Rh(III)-catalyzed ortho-selective C-H activation and tandem oxidative olefination-cyclization of aryl sulfonamides is described. The protocol has been applied to various substrates with good functional group tolerance.

机译：描述了有效的Rh（III）催化的芳基磺酰胺邻位选择性C-H活化和串联氧化烯化环化反应。该协议已应用于具有良好官能团耐受性的各种底物。

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《RSC Advances》 |2014年第93期|共6页
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Ding Qiuping; Liu Tong; Zheng Qiang; Zhang Yadong; Long Ling; Peng Yiyuan;
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正文语种 eng
中图分类化学;
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1. Rh(III)-catalyzed tandem oxidative olefination-cyclization of aryl sulfonamides [J] . Ding Qiuping, Liu Tong, Zheng Qiang, RSC Advances . 2014,第93期

机译：Rh（III）催化的芳基磺酰胺串联氧化烯化环化反应
2. Stereoselective Synthesis of Functionalized 1,3-Disubstituted Isoindolines via Rh(III)-Catalyzed Tandem Oxidative Olefination-Cyclization of 4-Aryl-cyclic Sulfamidate-5-Carboxylates [J] . Achary Raghavendra, Jung In -A, Son Se-Mi, The Journal of Organic Chemistry . 2017,第14期

机译：通过RH（III）的官能化1,3-二取代异吲哚啉酮的立体选择性合成 - 催化串联氧化烯烃 - 环化4-芳基环状磺酰胺-5-羧酸盐
3. Rh(III)-catalyzed tandem oxidative olefination-michael reactions between aryl carboxamides and alkenes [J] . Wang F., Song G., Li X. Organic letters . 2010,第23期

机译：Rh（III）催化的芳基羧酰胺和烯烃之间的串联氧化烯化反应
4. The Rhodium(I)-Catalyzed Alkylation of Aryl Sulfonamides with Alkenes through a Bidentate Chelating System and Related Mechanistic Studies [C] . Supriya Rej, Naoto Chatani 日本化学会春季年会講演予稿集 . 2018

机译：铑（I）通过双直齿螯合系统和相关机械研究 - 用烯烃烷基烷基化烷基化烷基化。
5. I. Tertiary aryl sulfonamides as new cross coupling partners for nickel catalyzed Kumada-Corriu-Tamao reductive and carbon-carbon bond forming cross coupling reactions. II. N-sulfonyl deprotection under mild nickel(0) catalyzed Kumada-Corriu-Tamao coupling conditions and development of the N-Ans protecting group. III. Synthesis and application of 3,3'-di-(2-pyridyl)-1,1'-bi-2-naphthol ligands [D] . Milburn, Robert Ronald 2004

机译：I.叔芳基磺酰胺作为镍催化的Kumada-Corriu-Tamao还原和碳-碳键形成交叉偶联反应的新交叉偶联伴侣。二。在温和的镍（0）下N-磺酰基脱保护催化了Kumada-Corriu-Tamao偶联条件和N-Ans保护基的发展。三， 3,3'-二-（2-吡啶基）-1,1'-bi-2-萘酚配体的合成及应用
6. Rh(ii)-catalyzed branch-selective C–H alkylation of aryl sulfonamides with vinylsilanes [O] . Supriya Rej, Naoto Chatani 2020

机译：Rh（ii）催化芳基磺酰胺与乙烯基硅烷的支链选择性C–H烷基化
7. Rhodium(III)-catalyzed oxidative olefination of N-allyl sulfonamides [O] . Shui Hu, Dongqi Wang, Jiexiang Liu, 2013

机译：Rhodium(III)-catalyzed oxidative olefination of N-allyl sulfonamides
8. Specific Oxidation of (Rh(CO)2Cl)2 by O2 via the Coordination of in Situ Generated HOOH. Implications for the RH(III)/Cu(II)-Catalyzed O2 Oxidation of 1-Alkenes to 2-Ketones [R] . Nyberg, E. D., Pribich, D. C., Drago, R. S. 1983

机译：O2（Rh（CO）2Cl）2通过原位生成的HOOH的配位氧化（Rh（CO）2Cl）2。 RH（III）/ Cu（II）催化氧化1-烯烃氧化成2-酮的意义

Rh(III)-catalyzed tandem oxidative olefination-cyclization of aryl sulfonamides

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