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The availability of Cd in aerobically and anaerobically incubated sewagesludge amended by bentonite

机译:膨润土对需氧和厌氧培养的污泥中镉的有效性

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During the evaluation of sewage sludge application on the agricultural land, the total content of potentially toxic elements usually plays a major role, but only available portion of element can be taken by plants, Main objective of the investigation was focused on determination of Cd availability in sewage sludge incubated under aerobic and anaerobic environment and amended by bentonite. Stabilised sludges from five different locations with different properties were incubated for eight month,.; with presence of air (aerated every other week) and without air (pressed into pot, covered and scaled) under controlled conditions (20 degreesC, 80% humidity). Each sludge was incubated as control treatment and with addition of two rates of bentonite in three replications. The available content of Cd was extracted by I mol.l(-1) NH4NO3 every other month and sequential extraction was made twice during incubation, Results showed great differences in Cd availability among tested sludges, Aerobically incubated sludges increased mean amount of mobile Cd in control as well as in bentonite treatments during incubation. Sludge incubated under anaerobic conditions released majority of Cd at the end of incubation. The application of bentonite decreased mean Cd availability under both conditions. Sequential analyses showed transformation of Cd bounds and Cd movement into labile exchangeable and oxide fractions in sludges incubated with presence of air and stable Cd distribution in sludge incubated under lack of air.
机译:在评估农业土地上的污水污泥施用量时,潜在有毒元素的总含量通常起主要作用,但植物只能吸收元素的可用部分,研究的主要目标集中在确定土壤中Cd的有效性。污水污泥在好氧和厌氧环境下培养并经膨润土修正。将来自五个不同位置,具有不同特性的稳定污泥孵育八个月。在受控条件下(20摄氏度,80%湿度)在有空气存在的情况下(每隔一周进行一次通气)而在没有空气的情况下(将其压入锅中,盖好并缩放)将每种污泥孵育作为对照处理,并在三个重复中添加两种速率的膨润土。每隔1个月用1 mol。(-1)NH4NO3萃取Cd的有效含量,并在温育过程中进行两次连续萃取,结果显示测试污泥中Cd的利用率差异很大,有氧培养的污泥增加了Cd中可移动Cd的平均值控制以及在培养过程中的膨润土处理。在厌氧条件下温育的污泥在温育结束时释放出大​​部分的镉。在两种情况下,膨润土的施用均降低了Cd的平均利用率。顺序分析表明,在空气存在下培养的污泥中,Cd的结合和Cd移动转化为不稳定的可交换部分和氧化物部分,而在缺乏空气下培养的污泥中的Cd分布稳定。

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