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EPR and UV spectroscopic investigations of sucrose irradiated with heavy-ion particles

机译:EPR和UV光谱研究重离子粒子照射的蔗糖

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Crystalline sucrose irradiated with C and Si ions is investigated with EPR and UV spectroscopy. Samples are treated at different doses of radiation in the region 20-300 Gy and linear energy transfer (LET) values of 39.6, 49 and 58 keV mu m(-1) for C ions and 60 keV mu m(-1) for Si ions. All samples exhibit identical EPR spectra due to radiation-induced stable sucrose radicals. At given constant LET the EPR signal responses are linear to the absorbed doses of Si and C ions. Water solutions of irradiated sucrose exhibit UV absorption maximum at 267 nm due to the product of radical recombination. The intensity of this band is stronger at irradiation with Si than with C ions. UV absorption is more sensitive to heavy-ion species irradiation than the EPR signals.
机译:用EPR和UV光谱研究了用C和Si离子辐照的结晶蔗糖。在20-300 Gy范围内以不同的辐射剂量处理样品,C离子的线性能量转移(LET)值分别为39.6、49和58 keVμm(-1),Si的线性能量转移(LET)值为60 keVμm(-1)离子。由于辐射诱导的稳定的蔗糖自由基,所有样品均表现出相同的EPR光谱。在给定的恒定LET下,EPR信号响应与Si和C离子的吸收剂量呈线性关系。由于自由基重组的产物,辐照蔗糖的水溶液在267 nm处表现出最大的UV吸收。该带的强度在用Si辐照时比用C离子强。与EPR信号相比,UV吸收对重离子物质辐射更敏感。

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