Dissolution of WWER-1000 Spent Nuclear Fuel in a Weakly Acidic Solution of Iron Nitrate and Recovery of Actinides and Rare Earth Elements with TBP Solutions

摘要

It is demonstrated on real solutions of samples of spent nuclear fuel (SNF) from WWER-1000 reactors (1000-MW_(el) water-cooled water-moderated energy reactors) that weakly acidic solutions of iron(III) nitrate at the molar ratio Fe(III) : U ≥ 2.0 dissolve SNF with quantitative transfer of U and Pu into the solution. In the process, Fe partially precipitates in the form of a basic salt precipitate together with a part of the fission products (>90% of Ru, ～90% of Mo, >60% of Tc, and 40% of Zr) already in the step of the fuel dissolution. Cs, Eu, and Am pass into the solution together with U and Pu. With the required conditions followed, U and Pu can be separated from the solution by precipitation of their peroxides or quantitatively extracted from this solution with 30% TBP in Isopar L. The presence of ≥1 M Fe(NO_3)_3 in the solution considerably increases the distribution ratios of TPE and REE, which allows their recovery from a weakly acidic nitrate solution to be also performed with 30% TBP in a diluent. This process can serve in the future as a basis for the development of a new integrated technology combining the PUREX process with TPE partitioning using a common extractant.