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Rate-limiting Steps, rate-determining Parameters, adn apparent activation energy of stepwise reactions, 2. Simple stepwise consecutive catalytic reactions linear in respect to intermediates

机译:限速步骤,限速参数,逐步反应的表观活化能2,简单的逐步连续催化反应,相对于中间体呈线性

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摘要

The paper considers the application of a recently suggested mahtematically correct approach for determining the rate-limiting steps, rate-determining parameters as well as the apparent activation energy for the steady cocurrence of simple stepwise consecutive catalytic reactions which are linear in respect ot catalytic intermediates. Under consideration are situations of both the small and large coverage of the surface with catalytic intermediates.
机译:本文考虑了最近提出的一种在数学上正确的方法的应用,该方法可用于确定限速步骤,速率确定参数以及表观活化能,以稳定地同时发生简单的连续催化反应,这些催化反应对于催化中间体是线性的。正在考虑用催化中间体覆盖大大小小的情况。

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